PVTx properties in the gas phase for difluoromethane (HFC-32) plus pentafluoroethane (HFC-125)

被引:8
作者
Meng, L [1 ]
Duan, YY [1 ]
Chen, Q [1 ]
机构
[1] Tsing Hua Univ, Dept Thermal Engn, Key Lab Thermal Sci & Power Engn, Beijing 100084, Peoples R China
关键词
D O I
10.1021/je0497505
中图分类号
O414.1 [热力学];
学科分类号
摘要
Gaseous PVT property measurements for difluoromethane (HFC-32) + pentafluoroethane (HFC-125) mixtures at 0.8191 (66.25 mass %), 0.5794 (37.38 mass %), and 0.4320 (24.79 mass %) mole fractions of HFC-32 are presented. Two hundred PVTx data points of this binary system were measured using Burnett isochoric methods in the range of temperature from (303.15 to 373.15) K, for pressures up to 3.246 MPa, and for densities up to 121 kg(.)m(-3). The experimental uncertainties are estimated to be within +/-10 mK for temperature, +/-0.3 kPa for pressure, 10.10% for density, and 0.1 mol % for composition. The temperature dependence of the second and third virial coefficients, along with the cross second and third virial coefficients, was also determined.
引用
收藏
页码:1821 / 1826
页数:6
相关论文
共 11 条
[1]   VAPOR-PRESSURES AND GAS-PHASE (P, RHO(N), T) VALUES FOR CF3CHF2 (R125) [J].
BOYES, SJ ;
WEBER, LA .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1995, 27 (02) :163-174
[2]  
Dymond J. D., 2002, VIRIAL COEFFICIENTS, V21
[3]   PVT PROPERTIES, VAPOR-PRESSURES AND CRITICAL PARAMETERS OF HFC-32 [J].
FU, YD ;
HAN, LZ ;
ZHU, MS .
FLUID PHASE EQUILIBRIA, 1995, 111 (02) :273-286
[4]  
GUPTA D, 1996, THESIS TEXAS A M U
[5]   PVTx properties of difluoromethane plus pentafluoroethane (R-32+125) and difluoromethane plus pentafluoroethane plus 1,1,1,2-tetrafluoroethane (R-32+125+134a) [J].
Kiyoura, H ;
Takebe, J ;
Uchida, H ;
Sato, H ;
Watanabe, K .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (06) :1409-1413
[6]   Measurements of PVTx properties of refrigerant mixture HFC-32+HFC-125 in the gaseous phase [J].
Sato, T ;
Kiyoura, H ;
Sato, H ;
Watanabe, K .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1996, 17 (01) :43-54
[7]   PVT PROPERTY MEASUREMENTS FOR DIFLUROMETHANE [J].
SATO, T ;
SATO, H ;
WATANABE, K .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (04) :851-854
[8]  
TILLNERROTH R, 1998, THERMODYNAMIC PROPER
[9]  
WEBER LA, 1994, INT J THERMOPHYS, V15, P871
[10]   Ideal-gas heat capacities and virial coefficients of HFC refrigerants [J].
Yokozeki, A ;
Sato, H ;
Watanabe, K .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1998, 19 (01) :89-127