Single-Crystal to Single-Crystal Photochemical Structural Transformations of Interpenetrated 3D Coordination Polymers by [2+2] Cycloaddition Reactions

被引：222

作者：

Mir, Mohammad Hedayetullah ^{[1
]}

Koh, Lip Lin ^{[1
]}

Tan, Geok Kheng ^{[1
]}

Vittal, Jagadese J. ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 02期

关键词：

cycloaddition; organic-inorganic hybrid composites; photochemistry; topochemistry; zinc; SOLID-STATE POLYMERIZATION; PHOTODIMERIZATION; CONSTRUCTION; CONVERSION; MOLECULES; ASSEMBLIES; REACTIVITY; FRAMEWORK; STACKING; COMPLEX;

D O I：

10.1002/anie.200905898

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

"Chemical Equation Presented" Photosensitive pillars: Perfectly aligned C = C bonds in frans-1,2-bis(4-pyridyl)ethene ligand pairs undergo 100 % photochemical [2+2] cycloaddition reactions in interpenetrated 3D coordination polymers, accompanied by single-crystal to single-crystal (SCSC) transformation (see scheme). © 2010 Wiley-VCH Verlag GmbH &. Co. KGaA.

引用

页码：390 / 393

页数：4

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