Synthesis and Characterization of 1,2-Benzenedimethyloxy Substituted Novel Ball-Type and Mononuclear Metallo Phthalocyanines

被引：0

作者：

Yazici, Aysegul ^{[1
]}

Dalbul, Nida ^{[1
]}

Salih, Bekir ^{[2
]}

机构：

[1] Firat Univ, Fac Sci, Dept Chem, TR-23119 Elazig, Turkey

[2] Hacettepe Univ, Fac Sci, Dept Chem, TR-06532 Ankara, Turkey

来源：

JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN | 2014年 / 36卷 / 04期

关键词：

Ball-type phthalocyanine; Zinc; Lutetium; GAS-SENSING PROPERTIES; HETERO-DINUCLEAR PHTHALOCYANINES; ZINC-PHTHALOCYANINE; OXYGEN REDUCTION; ELECTROCATALYTIC PROPERTIES; PERFORMANCE; CLAMSHELL; TRIAZINE;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The phthalodinitrile derivative 1 was synthesized by the reaction of 1,2-benzenedimethanol and 4-nitrophthalonitrile in dry DMF in the presence of K2CO3 by the common method of nucleophilic substitution of an activated nitro group in an aromatic ring. The template reaction of 1 with the corresponding metal salts gave the novel mono-nuclear ZnPc 2 and ball-type metallophthalocyanine LuPc2 3. In this study, we have used the "heating of the solid phase'' method for the synthesis of novel ball-type LuPc2 3 phthalocyanines. Mono-nuclear ZnPc 2 phthalocyanine was prepared by reflax in solvent. Mono and ball-type phthalocyanines were characterized by elemental analyses, FT-IR, H-1-NMR, C-13-NMR, UV-vis and MALDI-TOF MS spectral data.

引用

页码：707 / 711

页数：5

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