Mass Production, Enhanced Visible Light Photocatalytic Efficiency, and Application of Modified ZnO Nanocrystals by Carbon Dots

被引:50
作者
Zhang, Xiao-Yan [1 ]
Liu, Jin-Ku [1 ]
Wang, Jian-Dong [1 ]
Yang, Xiao-Hong [2 ]
机构
[1] E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China
[2] Chizhou Univ, Dept Chem, Chizhou 247000, Peoples R China
基金
中国国家自然科学基金;
关键词
DOPED ZNO; QUANTUM DOTS; METAL-IONS; NANOPARTICLES; TIO2; NANOWIRES; HYBRID;
D O I
10.1021/ie504444w
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The carbon dot (C-ZnO NCs) modified zinc oxide with novel visible-light catalytic abilities was mass produced by combustion method. During the formation process, the generated gas of reagents under high temperature can effectively break the product into small particles. Meanwhile, a certain amount of carbon dots have been formed and loaded on the surface of ZnO NCs. The results suggest that the carbon dots have a huge impact on the photocatalytic performance. Specifically, when the molar ratio of glycine to zinc nitrate was 2:1, the product was a monodisperse particle with an average diameter of about 7080 nm and BET specific surface area of 11.88 m(2)center dot g(-1), which exhibited the best catalytic efficiency. The degradation process of Rh. B can be completed within 15 min, with an increase of 433.3% compared with pure ZnO materials (80 min). The present study is not only significant for improving large-scale production of modified ZnO NCs but also for suggesting practical application fields such as environmental catalysts.
引用
收藏
页码:1766 / 1772
页数:7
相关论文
共 45 条
[21]   Improved visible-light photocatalytic activity of porous carbon self-doped ZnO nanosheet-assembled flowers [J].
Liu, Shengwei ;
Li, Chuan ;
Yu, Jiaguo ;
Xiang, Quanjun .
CRYSTENGCOMM, 2011, 13 (07) :2533-2541
[22]   High Photocatalytic Activity of ZnO-Carbon Nanofiber Heteroarchitectures [J].
Mu, Jingbo ;
Shao, Changlu ;
Guo, Zengcai ;
Zhang, Zhenyi ;
Zhang, Mingyi ;
Zhang, Peng ;
Chen, Bin ;
Liu, Yichun .
ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (02) :590-596
[23]   Ferromagnetism in Carbon-Doped Zinc Oxide Systems [J].
Nagare, B. J. ;
Chacko, Sajeev ;
Kanhere, D. G. .
JOURNAL OF PHYSICAL CHEMISTRY A, 2010, 114 (07) :2689-2696
[24]   Synthesis of carbon doped ZnO with a porous structure and its solar-light photocatalytic properties [J].
Ouyang Haibo ;
Huang Jian Feng ;
Li Cuiyan ;
Cao Liyun ;
Fei Jie .
MATERIALS LETTERS, 2013, 111 :217-220
[25]   VC, NBC AND TAC WITH VARYING CARBON CONTENT STUDIED BY ESCA [J].
RAMQVIST, L ;
HAMRIN, K ;
JOHANSSON, G ;
GELIUS, U ;
NORDLING, C .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1970, 31 (12) :2669-+
[26]   Electrodeposition of Al-doped ZnO Nanoflowers with Enhanced Photocatalytic Performance [J].
She, Guangwei ;
Chen, Xue ;
Wang, Yao ;
Qi, Xiaopeng ;
Mu, Lixuan ;
Shi, Wensheng .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2012, 12 (03) :2756-2760
[27]   Ga2O3 and GaN semiconductor hollow spheres [J].
Sun, XM ;
Li, YD .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (29) :3827-3831
[28]   p-type conduction in unintentional carbon-doped ZnO thin films [J].
Tan, S. T. ;
Sun, X. W. ;
Yu, Z. G. ;
Wu, P. ;
Lo, G. Q. ;
Kwong, D. L. .
APPLIED PHYSICS LETTERS, 2007, 91 (07)
[29]   Tailoring surface groups of carbon quantum dots to improve photoluminescence behaviors [J].
Tian, Ruixue ;
Hu, Shengliang ;
Wu, Lingling ;
Chang, Qing ;
Yang, Jinlong ;
Liu, Jun .
APPLIED SURFACE SCIENCE, 2014, 301 :156-160
[30]   Light-dependent controlled synthesis and photocatalytic properties of stable Ag3 nanocrystals [J].
Wang, Jian-Dong ;
Liu, Jin-Ku ;
Luo, Chong-Xiao ;
Yang, Xiao-Hong .
MATERIALS RESEARCH BULLETIN, 2014, 60 :783-793