Mass Production, Enhanced Visible Light Photocatalytic Efficiency, and Application of Modified ZnO Nanocrystals by Carbon Dots

被引:50
作者
Zhang, Xiao-Yan [1 ]
Liu, Jin-Ku [1 ]
Wang, Jian-Dong [1 ]
Yang, Xiao-Hong [2 ]
机构
[1] E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China
[2] Chizhou Univ, Dept Chem, Chizhou 247000, Peoples R China
基金
中国国家自然科学基金;
关键词
DOPED ZNO; QUANTUM DOTS; METAL-IONS; NANOPARTICLES; TIO2; NANOWIRES; HYBRID;
D O I
10.1021/ie504444w
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The carbon dot (C-ZnO NCs) modified zinc oxide with novel visible-light catalytic abilities was mass produced by combustion method. During the formation process, the generated gas of reagents under high temperature can effectively break the product into small particles. Meanwhile, a certain amount of carbon dots have been formed and loaded on the surface of ZnO NCs. The results suggest that the carbon dots have a huge impact on the photocatalytic performance. Specifically, when the molar ratio of glycine to zinc nitrate was 2:1, the product was a monodisperse particle with an average diameter of about 7080 nm and BET specific surface area of 11.88 m(2)center dot g(-1), which exhibited the best catalytic efficiency. The degradation process of Rh. B can be completed within 15 min, with an increase of 433.3% compared with pure ZnO materials (80 min). The present study is not only significant for improving large-scale production of modified ZnO NCs but also for suggesting practical application fields such as environmental catalysts.
引用
收藏
页码:1766 / 1772
页数:7
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