Facile Exfoliation of Single-Crystalline Copper Alkylphosphates to Single-Layer Nanosheets and Enhanced Supercapacitance

被引：21
作者：
Bhat, Gulzar A. [1 ]
Haldar, Sattwick [2 ,3 ]
Verma, Sonam [1 ]
Chakraborty, Debanjan [2 ,3 ]
Vaidhyanathan, Ramanathan [2 ,3 ]
Murugavel, Ramaswamy [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India
[2] Indian Inst Sci Educ & Res, Dept Chem, Pune 411008, Maharashtra, India
[3] Indian Inst Sci Educ & Res, Ctr Energy Sci, Pune 411008, Maharashtra, India
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 47期
关键词：
copper alkylphosphate; exfoliation; single-layer nanosheets; supercapacitors; van der Waals solids; ORGANIC FRAMEWORK NANOSHEETS; METAL; DELAMINATION; PRECURSORS;
D O I：
10.1002/anie.201910157
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Manipulation of low-dimensional solids through soft chemical routes is an elegant way to realize newer materials. A new family of single-crystalline transition-metal layered organophosphates, with about 185000 metal phosphate layers in a single crystal, can be exfoliated to a single-layer nanosheet by a facile and rapid solvent assisted method. This exfoliation aids the formation of high-surface-area pyrophosphates with enhanced supercapacitance.
引用
收藏
页码：16844 / 16849
页数：6
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