Facile Exfoliation of Single-Crystalline Copper Alkylphosphates to Single-Layer Nanosheets and Enhanced Supercapacitance

被引：21

作者：

Bhat, Gulzar A. ^{[1
]}

Haldar, Sattwick ^{[2
,3
]}

Verma, Sonam ^{[1
]}

Chakraborty, Debanjan ^{[2
,3
]}

Vaidhyanathan, Ramanathan ^{[2
,3
]}

Murugavel, Ramaswamy ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India

[2] Indian Inst Sci Educ & Res, Dept Chem, Pune 411008, Maharashtra, India

[3] Indian Inst Sci Educ & Res, Ctr Energy Sci, Pune 411008, Maharashtra, India

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 47期

关键词：

copper alkylphosphate; exfoliation; single-layer nanosheets; supercapacitors; van der Waals solids; ORGANIC FRAMEWORK NANOSHEETS; METAL; DELAMINATION; PRECURSORS;

D O I：

10.1002/anie.201910157

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Manipulation of low-dimensional solids through soft chemical routes is an elegant way to realize newer materials. A new family of single-crystalline transition-metal layered organophosphates, with about 185000 metal phosphate layers in a single crystal, can be exfoliated to a single-layer nanosheet by a facile and rapid solvent assisted method. This exfoliation aids the formation of high-surface-area pyrophosphates with enhanced supercapacitance.

引用

页码：16844 / 16849

页数：6

共 39 条

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