Thermodynamic properties of binary mixtures of two alcohols. An application of the SERAS model to the description of very small excess molar functions

被引:6
|
作者
Gepert, M.
Hachula, B.
机构
[1] University of Silesia, Institute of Chemistry, 40-006 Katowice
关键词
D O I
10.1016/j.molliq.2006.12.026
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A theoretical description of excess molar volumes and excess molar enthalpies of 13 binary mixtures using the SERAS model equations is presented. The results are collected and their physical reliability is discussed. A new idea was tested to improve the quality of the description of very small νE and hE functions without increasing the number of adjustable parameters of the model used. © 2007 Elsevier B.V. All rights reserved.
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页码:196 / 206
页数:11
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