Functionalization of single-walled carbon nanotubes with Prussian blue

被引:128
作者
Zhang, YJ
Wen, Y
Liu, Y
Li, D
Li, JH [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
carbon nanotubes; Prussian blue; interaction; electrochemical properties;
D O I
10.1016/j.elecom.2004.09.016
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Chemical functionalization of single-walled carbon nanotubes (SWNTs) has constructed plenty of new structures with ample new properties into them. But the modification was often confined to organic molecules, either by covalence or non-covalence. In this report, SWNTs were successfully functionalized with one kind of electroactive inorganic compounds: Prussian blue (PB). And the molecular interactions between them were firstly investigated. Interestedly, pi-pi stacking interaction coupled with ionic interaction was found between SWNTs and PB. The electrochemical properties of SWNTs-PB were also investigated. It would pave a new pathway to manipulate molecular entities of SWNTs by cooperation with functional inorganic electroactive compounds. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:1180 / 1184
页数:5
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