Extraction of selected metals from spent hydrodesulfurization catalyst using alkali leaching agent

被引：24

作者：

Yaras, Ali ^{[1
]}

Arslanoglu, Hasan ^{[2
]}

机构：

[1] Bartin Univ, Dept Met & Mat Engn, Fac Engn Architecture & Design, TR-74110 Bartin, Turkey

[2] Kirsehir Ahi Evran Univ, Dept Chem & Proc Engn, Fac Engn & Architecture, Kirsehir, Turkey

来源：

SEPARATION SCIENCE AND TECHNOLOGY | 2020年 / 55卷 / 11期

关键词：

Spent HDS catalyst; molybdenum; aluminum; leaching; kinetic; HYDROTREATING CATALYSTS; REFINERY CATALYSTS; FUTURE-TRENDS; RECOVERY; NI-MO/AL2O3; MOLYBDENUM; MANAGEMENT; MANGANESE; WASTE; ZINC;

D O I：

10.1080/01496395.2019.1673412

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aim of present study is to examine the dissolution and kinetics of valuable metals from spent hydrodesulfurization catalyst using potassium hydroxide. Due to low solubility of metal oxides of Ni and Co in alkali medium, only the recovery of Mo and Al was investigated. Optimum roasting temperature and time were determined 600?C and 60 min., respectively. The maximum dissolution yields of Mo (83.54%) and Al (36.89%) were reached under optimum leaching conditions. The leaching behavior of both metals is represented by the shrinking core model and liquid film diffusion is controlled the process. Activation energies found to be 14.71 kJ/mol and 17.84 kJ/mol for Mo and Al, respectively.

引用

页码：2037 / 2048

页数：12

共 43 条

[1]

AbsiHalabi M, 1997, HYDROCARB PROCESS, V76, P45

[2] A review of metal recovery from spent petroleum catalysts and ash [J].

Akcil, Ata ;

Veglio, Francesco ;

Ferella, Francesco ;

Okudan, Mediha Demet ;

Tuncuk, Aysenur .

WASTE MANAGEMENT, 2015, 45 :420-433

[3] Comparison between deactivation pattern of catalysts in fixed-bed and ebullating-bed residue hydroprocessing units [J].

Al-Dalama, K. ;

Stanislaus, A. .

CHEMICAL ENGINEERING JOURNAL, 2006, 120 (1-2) :33-42

[4] SELECTIVE DISSOLUTION OF CRITICAL METALS FROM DIESEL AND NAPTHA SPENT HYDRODESULFURIZATION CATALYSTS [J].

ANGELIDIS, TN ;

TOURASANIDIS, E ;

MARINOU, E ;

STALIDIS, GA .

RESOURCES CONSERVATION AND RECYCLING, 1995, 13 (3-4) :269-282

[5] Bioleaching of spent refinery catalysts: A review [J].

Asghari, I. ;

Mousavi, S. M. ;

Amiri, F. ;

Tavassoli, S. .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2013, 19 (04) :1069-1081

[6] The mineralogy of bauxite for producing smelter-grade alumina [J].

Authier-Martin, M ;

Forté, G ;

Ostap, S ;

See, J .

JOM-JOURNAL OF THE MINERALS METALS & MATERIALS SOCIETY, 2001, 53 (12) :36-40

[7] Recovery of zinc and manganese from alkaline and zinc-carbon spent batteries [J].

De Michelis, I. ;

Ferella, F. ;

Karakaya, E. ;

Beolchini, F. ;

Veglio, F. .

JOURNAL OF POWER SOURCES, 2007, 172 (02) :975-983

[8] Hydroprocessing catalysts regeneration and recycling [J].

Dufresne, Pierre .

APPLIED CATALYSIS A-GENERAL, 2007, 322 :67-75

[9] Extraction of metals from spent hydrotreating catalysts: Physico-mechanical pre-treatments and leaching stage [J].

Ferella, Francesco ;

Ognyanova, Albena ;

De Michelis, Ida ;

Taglieri, Giuliana ;

Veglio, Francesco .

JOURNAL OF HAZARDOUS MATERIALS, 2011, 192 (01) :176-185

[10] Spent refinery catalysts: Environment, safety and utilization [J].

Furimsky, E .

CATALYSIS TODAY, 1996, 30 (04) :223-286

← 1 2 3 4 5 →