A 3D Homochiral Mn(II) Coordination Polymer Based on the Ligand 2,2′-(Ethane-1,2-diylbis(oxy)) Dicinnamic Acid

被引：1

作者：

Chen Xin ^{[1
]}

Zhang Ming-Xing ^{[1
]}

Huang Kun-Lin ^{[1
]}

机构：

[1] Chongqing Normal Univ, Coll Chem, Chongqing 401331, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 37卷 / 06期

关键词：

chirality; coupled cinnamic acid; manganese; second harmonic generation; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; HELICAL CHAINS; MAGNETIC-PROPERTIES; CONSTRUCTION; PROPERTY; CHANNELS; SERIES;

D O I：

10.14102/j.cnki.0254-5861.2011-1868

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3D homochiral coordination polymer [Mn(edca)](n) (1) was synthesized from a flexible coupled cinnamic acid ligand, 2,2'-(ethane-1,2-diylbis(oxy)) dicinnamic acid (H(2)edca) and MnCl2 center dot 4H(2)O under solvothermal conditions. The complex crystallizes in orthorhombic, space group P2(1)2(1)2(1) with a = 5.5785(8), b = 13.0393(18), c = 23.133(3) angstrom, V = 1682.7(4) angstrom(3), Mr = 407.27, Dc = 1.608 Mg/cm(3), F(000) = 836, Z = 4, the final R = 0.0240 and wR = 0.0590 for 2983 observed reflections (I > 2 sigma(I)). In 1, the edca(2+) anions alternately bridge the Mn(II) cations to form one-dimensional (1D) infinite helical chains of [Mn(edca)](n), which are further connected by the ligands generating a three-dimensional (3D) homochiral network. The photoluminescence of 1 was also investigated in solid state at ambient temperature.

引用

页码：966 / 972

页数：7

共 50 条

[21] A Novel Luminescent Zinc(II) Coordination Polymer with 2D → 3D Polythreaded Motif
Qin Ye-Yan
Zhang Xin
Shen Yi-Cheng
Yao Yuan-Gen
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (09) : 1399 - 1404
[22] Synthesis and Characterization of New 2D Coordination Polymers based on Mn(NCS)2 and Ni(NCS)2 with 1,2-Bis(4-pyridyl)-ethane as Co-Ligand
Woehlert, Susanne
Fink, Lothar
Schmidt, Martin U.
Naether, Christian
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (12-13): : 2186 - 2194
[23] A novel 2D sandwich layered neodymium coordination polymer based on 2,2′-bipyridyl-4,4′-dicarboxylate ligand
Yuan, Long-fei
Li, Jun
Liu, Rui-ping
Liu, Bin
Guo, Hui
Zhang, Feng-xing
INORGANICA CHIMICA ACTA, 2013, 404 : 197 - 200
[24] First 3D coordination polymer built from Ho(III) and 2-aminoterephthalate ligand
Almasi, Miroslav
Zelenak, Vladimir
Galdun, Ladislav
Kuchar, Juraj
INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 39 : 39 - 42
[25] Synthesis and Characterization of a New 3D Pillared Bilayer Cd(II) Coordination Polymer Based on 6,6′-Dinitro-2,2′,4,4′-biphenyltetracarboxylic Acid
Wang Ji-Wu
Su Yong-Chao
Wang Ji-Jiang
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2015, 34 (09) : 1385 - 1390
[26] A 3D supramolecular architecture based on 2,2′-oxybis(benzoic acid) and trans-1,2-bis(4-pyridyl) ethylene as ligands for Co(II)
Tang, Long
Zhang, Juan
Liu, Xiao-Xia
Wang, Ji-Jiang
Fu, Feng
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2017, 72 (06): : 397 - 401
[27] Temperature-Dependant Assemblies of Cu(II) Coordination Polymers and In Situ Ligand Reaction Based on 2,2'-Bipyridine-3,3',6,6'-Tetracarboxylic acid
Kang, Yifan
Liang, Xiqiang
Jin, Meng
Li, Yuanfeng
Cao, Junqi
Sun, Ruiting
Zheng, Xin
Lu, Meijin
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2017, 27 (04) : 1063 - 1071
[28] Syntheses and Crystal Structures of Three Cu(II) Complexes Based on 2,2 2'-(ethane-1,2-diyl) bis(1H-imidazole-4, 5-dicarboxylic Acid)
Zhao, Lei
Wang, Zhiwu
Zhao, Dong
Meng, Xiangru
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2014, 44 (02) : 195 - 202
[29] A pH-controlled fluorescent sensor and logic gate based on a 1D → 2D → 3D Cd(II)-containing coordination polymer
Kan, Wei-Qiu
Wen, Shi-Zheng
POLYHEDRON, 2017, 128 : 169 - 174
[30] 3,3′-Di(pyrazinamoyl)-2,2′-bipyridine: rational ligand design for the self-assembly of a 1-D coordination polymer
Hurley, Nicholas J.
Rawson, Jeremy M.
Pilkington, Melanie
DALTON TRANSACTIONS, 2015, 44 (04) : 1866 - 1874

← 1 2 3 4 5 →