Manganese(III,IV) and manganese(III) oxide clusters trapped by copper(II) complexes

被引：28
|
作者：
Yamashita, Satoshi
Shiga, Takuya
Kurashina, Masashi
Nihei, Masayuki
Nojiri, Hiroyuki
Sawa, Hiroshi
Kakiuchi, Toru
Oshio, Hiroki
机构：
[1] Univ Tsukuba, Dept Chem, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan
[2] Tohoku Univ, Mat Res Inst, Aoba Ku, Sendai, Miyagi, Japan
[3] High Energy Accelerator Res Org, Inst Mat Res Sci, Tsukuba, Ibaraki 3050801, Japan
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 10期
关键词：
D O I：
10.1021/ic062258h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of quinquedentate Schiff base ligands with Mn and Cu ions afforded icosa- and hexadecanuclear mixed-metal clusters in which dinuclear Cu-II complexes trapped oxo-bridged [(Mn8Mn4O12)-Mn-III-O-IV] and [(Mn6O6)-O-III] cores, respectively. Maximum entropy method analysis for synchrotron X-ray diffraction data was used to determine the oxidation states of the Mn ions.
引用
收藏
页码：3810 / 3812
页数：3
相关论文
共 50 条
  • [31] Formation and transformation of manganese(III) intermediates in the photochemical generation of manganese(IV) oxide minerals
    Zhang, Tengfei
    Liu, Lihu
    Tan, Wenfeng
    Suib, Steven L.
    Qiu, Guohong
    CHEMOSPHERE, 2021, 262
  • [32] The titanium(IV), iron(III) and manganese(II) complexes of chrysin-4′-sulfonate
    Pusz, J
    Nitka, B
    Wolowiec, S
    POLISH JOURNAL OF CHEMISTRY, 2001, 75 (06) : 795 - 801
  • [33] REDOX CHEMISTRY OF MONONUCLEAR MANGANESE(II), BINUCLEAR MANGANESE(III) AND BINUCLEAR MIXED MANGANESE(II)-MANGANESE(III) COMPLEXES WITH 3-AMINOPYRAZINE-2-CARBOXYLATE IN DIMETHYLSULFOXIDE
    ARANCIBIA, V
    DELVALLE, MA
    BODINI, M
    TRANSITION METAL CHEMISTRY, 1995, 20 (02) : 179 - 184
  • [34] ISOLATION AND CHARACTERIZATION OF A SERIES OF DINUCLEAR COMPLEXES OF MANGANESE (II, III, IV) AND THEIR BIOLOGICAL RELEVANCE
    WIEGHARDT, K
    BOSSEK, U
    POHL, K
    RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1987, 106 (6-7): : 172 - 172
  • [35] INVESTIGATIONS OF CHROMIUM(III), MANGANESE(III), TIN(II) AND LEAD(II) DITHIOCARBAMATE COMPLEXES
    PRETI, C
    TOSI, G
    ZANNINI, P
    JOURNAL OF MOLECULAR STRUCTURE, 1980, 65 (AUG) : 283 - 292
  • [36] Complexes of N-phenyl-N′-2-furanthiocarbohydrazide with oxovanadium(IV), manganese(III), iron(III), cobalt(II), nickel(II), copper(II) and zinc(II)
    Nand K. Singh
    Surendra K. Kushawaha
    Archana Ayyagari
    Transition Metal Chemistry, 2001, 26 : 140 - 146
  • [37] COMPLEXES OF OXOVANADIUM(IV), CHROMIUM(III), MANGANESE(II), IRON(III) AND COBALT(II) WITH 1-AMIDINO-2-THIOUREAS
    ROY, NK
    SAHA, CR
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1984, 23 (06): : 484 - 487
  • [38] Complexes of N-phenyl-N′-2-furanthiocarbohydrazide with oxovanadium(IV), manganese(III), iron(III), cobalt(II), nickel(II), copper(II) and zinc(II)
    Singh, NK
    Kushawaha, SK
    Ayyagari, A
    TRANSITION METAL CHEMISTRY, 2001, 26 (1-2) : 140 - 146
  • [39] CONSTITUTION AND OXIDIZING PROPERTIES OF MATERIALS IN COPPER(II) OXIDE-MANGANESE(III) OXIDE SYSTEM
    DOLLIMOR.D
    TONGE, KH
    JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (10): : 1728 - &
  • [40] PHASE-DIAGRAM OF THE MANGANESE(II, III) AND COBALT(II, III) OXIDE SYSTEM
    CHALY, VP
    PASHKOVA, EV
    KRASAN, YP
    UKRAINSKII KHIMICHESKII ZHURNAL, 1981, 47 (08): : 881 - 883
12345