Manganese(III,IV) and manganese(III) oxide clusters trapped by copper(II) complexes

被引：28

作者：

Yamashita, Satoshi

Shiga, Takuya

Kurashina, Masashi

Nihei, Masayuki

Nojiri, Hiroyuki

Sawa, Hiroshi

Kakiuchi, Toru

Oshio, Hiroki

机构：

[1] Univ Tsukuba, Dept Chem, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

[2] Tohoku Univ, Mat Res Inst, Aoba Ku, Sendai, Miyagi, Japan

[3] High Energy Accelerator Res Org, Inst Mat Res Sci, Tsukuba, Ibaraki 3050801, Japan

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 10期

关键词：

D O I：

10.1021/ic062258h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of quinquedentate Schiff base ligands with Mn and Cu ions afforded icosa- and hexadecanuclear mixed-metal clusters in which dinuclear Cu-II complexes trapped oxo-bridged [(Mn8Mn4O12)-Mn-III-O-IV] and [(Mn6O6)-O-III] cores, respectively. Maximum entropy method analysis for synchrotron X-ray diffraction data was used to determine the oxidation states of the Mn ions.

引用

收藏

页码：3810 / 3812

页数：3

相关论文

共 27 条

[1] The chemistry of cobalt acetate .3. The isolation and crystal structure characterisation of the mixed valence octacobalt oligomer, [Co-8(O)(4)(CH3CO2)(6)(OMe)(4)]Cl-4(OHn)(4)center dot 6H(2)O (n=1 or 2), derived from the preparation of cobalt(III) acetate [J].

Beattie, JK ;

Hambley, TW ;

Klepetko, JA ;

Masters, AF ;

Turner, P .

POLYHEDRON, 1997, 16 (12) :2109-2112

[2] POSSIBLE HIGH-TC SUPERCONDUCTIVITY IN THE BA-LA-CU-O SYSTEM [J].

BEDNORZ, JG ;

MULLER, KA .

ZEITSCHRIFT FUR PHYSIK B-CONDENSED MATTER, 1986, 64 (02) :189-193

[3] Towards a synthetic model of the photosynthetic water oxidizing complex:: [Mn3O4(O2CMe)4(bpy)2] containing the [MnIV3(μ-O)4]4+ core [J].

Bhaduri, S ;

Pink, M ;

Christou, G .

CHEMICAL COMMUNICATIONS, 2002, (20) :2352-2353

[4] [L2MN2(MU-O)2(MU-O2)](CLO4)2 - THE 1ST BINUCLEAR (MU-PEROXO)DIMANGANESE(IV) COMPLEX (L = 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE) - A MODEL FOR THE S4-]S0 TRANSFORMATION IN THE OXYGEN-EVOLVING COMPLEX IN PHOTOSYNTHESIS [J].

BOSSEK, U ;

WEYHERMULLER, T ;

WIEGHARDT, K ;

NUBER, B ;

WEISS, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (17) :6387-6388

[5] PROBING THE MECHANISM OF WATER OXIDATION IN PHOTOSYSTEM-II [J].

BRUDVIG, GW ;

THORP, HH ;

CRABTREE, RH .

ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (10) :311-316

[6] MANGANESE CARBOXYLATE CHEMISTRY AND ITS BIOLOGICAL RELEVANCE [J].

CHRISTOU, G .

ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (09) :328-335

[7] Single-molecule magnets [J].

Christou, George ;

Gatteschi, Dante ;

Hendrickson, David N. ;

Sessoli, Roberta .

MRS Bulletin, 2000, 25 (11) :66-71

[8] THE MANGANESE AND CALCIUM-IONS OF PHOTOSYNTHETIC OXYGEN EVOLUTION [J].

DEBUS, RJ .

BIOCHIMICA ET BIOPHYSICA ACTA, 1992, 1102 (03) :269-352

[9] Polynuclear chromium(III) carboxylates. 3. Cyclic and cubane type hexachromium acetates [J].

Eshel, M ;

Bino, A .

INORGANICA CHIMICA ACTA, 2002, 329 (01) :45-50

[10] Voronoi deformation density (VDD) charges: Assessment of the Mulliken, Bader, Hirshfeld, Weinhold, and VDD methods for charge analysis [J].

Guerra, CF ;

Handgraaf, JW ;

Baerends, EJ ;

Bickelhaupt, FM .

JOURNAL OF COMPUTATIONAL CHEMISTRY, 2004, 25 (02) :189-210