Manganese(III,IV) and manganese(III) oxide clusters trapped by copper(II) complexes

被引：28

作者：

Yamashita, Satoshi

Shiga, Takuya

Kurashina, Masashi

Nihei, Masayuki

Nojiri, Hiroyuki

Sawa, Hiroshi

Kakiuchi, Toru

Oshio, Hiroki

机构：

[1] Univ Tsukuba, Dept Chem, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

[2] Tohoku Univ, Mat Res Inst, Aoba Ku, Sendai, Miyagi, Japan

[3] High Energy Accelerator Res Org, Inst Mat Res Sci, Tsukuba, Ibaraki 3050801, Japan

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 10期

关键词：

D O I：

10.1021/ic062258h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of quinquedentate Schiff base ligands with Mn and Cu ions afforded icosa- and hexadecanuclear mixed-metal clusters in which dinuclear Cu-II complexes trapped oxo-bridged [(Mn8Mn4O12)-Mn-III-O-IV] and [(Mn6O6)-O-III] cores, respectively. Maximum entropy method analysis for synchrotron X-ray diffraction data was used to determine the oxidation states of the Mn ions.

引用

页码：3810 / 3812

页数：3

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