Collision rate constant for non-spherical particles moving under shear flow

被引:2
|
作者
Gruy, Frederic [1 ]
Nortier, Patrice [1 ]
机构
[1] Ecole Natl Super Mines, 158 Cours Fauriel, F-42023 St Etienne 02, France
关键词
Shear aggregation; Convex particles; Anisotropic particles; Monte carlo simulation; Analytical modelling; COLLOIDAL DISPERSIONS; AGGREGATION; COAGULATION; KINETICS; SIMULATION; CLUSTERS;
D O I
10.1016/j.colsurfa.2017.03.037
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Taking into account the morphology of the particles in the aggregation dynamics is addressed theoretically in this paper. The rate constant or kernel of collision between particles with simple shapes (spheroids oblate and prolate, disc, needle) has been calculated from a Monte Carlo algorithm simulating shear aggregation. The corresponding data were used to build a model, which comes in the form of an empirical expression linking the rate constant of collision, the shear rate and three shape parameters describing each particle. This concise expression represents very well all the data issued from Monte Carlo calculation. Statistical analysis of the Monte Carlo calculations and the proposed model as well has been carefully achieved. (c) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:552 / 562
页数:11
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