Direct measurements of inverse magnetocaloric effects in metamagnetic shape-memory alloy NiCoMnIn

被引:154
作者
Kihara, T. [1 ]
Xu, X. [2 ]
Ito, W. [3 ]
Kainuma, R. [2 ]
Tokunaga, M. [1 ]
机构
[1] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan
[2] Tohoku Univ, Dept Mat Sci, Sendai, Miyagi 9808579, Japan
[3] Sendai Natl Coll Technol, Natori, Miyagi 9811239, Japan
关键词
TRANSITION; TRANSFORMATION;
D O I
10.1103/PhysRevB.90.214409
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
To clarify the electronic, lattice, and magnetic contribution to the inverse magnetocaloric effect (IMCE) in the metamagnetic shape-memory alloy Ni45Co5Mn50-xInx, magnetization, magnetocaloric effect, and specific-heat measurements were carried out in a wide range of fields and temperatures. The IMCEs of Ni45Co5Mn36.7In13.3 were directly measured as adiabatic temperature changes in pulsed fields of up to 15 T. A maximum temperature decrease of -12.8 K was observed. The low-temperature specific heats in both the austenitic and the martensitic phases of Ni45Co5Mn36.5In13.5 were measured by using steady fields. Through analyses of the data, the entropy changes in charge (1.2 J/kg K), spin (-29 J/kg K), and lattice (51 J/kg K) sectors were individually evaluated. The result demonstrates the dominant role of the lattice sector in inverse MCEs in this material.
引用
收藏
页数:6
相关论文
共 33 条
[11]   Development of high-speed polarizing imaging system for operation in high pulsed magnetic field [J].
Katakura, I. ;
Tokunaga, M. ;
Matsuo, A. ;
Kawaguchi, K. ;
Kindo, K. ;
Hitomi, M. ;
Akahoshi, D. ;
Kuwahara, H. .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2010, 81 (04)
[12]   Reversibility and irreversibility of magnetocaloric effect in a metamagnetic shape memory alloy under cyclic action of a magnetic field [J].
Khovaylo, V. V. ;
Skokov, K. P. ;
Gutfleisch, O. ;
Miki, H. ;
Kainuma, R. ;
Kanomata, T. .
APPLIED PHYSICS LETTERS, 2010, 97 (05)
[13]   Optical imaging and magnetocaloric effect measurements in pulsed high magnetic fields and their application to Ni-Co-Mn-In Heusler alloy [J].
Kihara, T. ;
Katakura, I. ;
Tokunaga, M. ;
Matsuo, A. ;
Kawaguchi, K. ;
Kondo, A. ;
Kindo, K. ;
Ito, W. ;
Xu, X. ;
Kainuma, R. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 577 :S722-S725
[14]   Adiabatic measurements of magneto-caloric effects in pulsed high magnetic fields up to 55 T [J].
Kihara, T. ;
Kohama, Y. ;
Hashimoto, Y. ;
Katsumoto, S. ;
Tokunaga, M. .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2013, 84 (07)
[15]   The influence of atomic order on the magnetic and structural properties of the ferromagnetic shape memory compound Ni2MnGa [J].
Kreissl, M ;
Neumann, KU ;
Stephens, T ;
Ziebeck, KRA .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (22) :3831-3839
[16]   Inverse magnetocaloric effect in ferromagnetic Ni-Mn-Sn alloys [J].
Krenke, T ;
Duman, E ;
Acet, M ;
Wassermann, EF ;
Moya, X ;
Mañosa, L ;
Planes, A .
NATURE MATERIALS, 2005, 4 (06) :450-454
[17]   Entropy change and effect of magnetic field on martensitic transformation in a metamagnetic Ni-Co-Mn-In shape memory alloy [J].
Kustov, S. ;
Corro, M. L. ;
Pons, J. ;
Cesari, E. .
APPLIED PHYSICS LETTERS, 2009, 94 (19)
[18]   A large and reproducible metamagnetic shape memory effect in polycrystalline Ni45Co5Mn37In13 Heusler alloy [J].
Li, Z. ;
Jing, C. ;
Zhang, H. L. ;
Yu, D. H. ;
Chen, L. ;
Kang, B. J. ;
Cao, S. X. ;
Zhang, J. C. .
JOURNAL OF APPLIED PHYSICS, 2010, 108 (11)
[19]  
Liu J, 2012, NAT MATER, V11, P620, DOI [10.1038/nmat3334, 10.1038/NMAT3334]
[20]   Pressure enhancement of the giant magnetocaloric effect in Tb5Si2Ge2 -: art. no. 137201 [J].
Morellon, L ;
Arnold, Z ;
Magen, C ;
Ritter, C ;
Prokhnenko, O ;
Skorokhod, Y ;
Algarabel, PA ;
Ibarra, MR ;
Kamarad, J .
PHYSICAL REVIEW LETTERS, 2004, 93 (13) :137201-1