Carbon-coated Mo3Sb7 composite as anode material for sodium ion batteries with long cycle life

被引：42
作者：
Li, Wei [1 ]
Hu, Chen [2 ]
Zhou, Min [1 ]
Tao, Hongwei [1 ]
Wang, Kangli [1 ]
Cheng, Shijie [1 ]
Jiang, Kai [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Adv Electromagnet Engn & Technol, Wuhan 430074, Peoples R China
[2] China Elect Power Res Inst, Beijing 100192, Peoples R China
来源：
JOURNAL OF POWER SOURCES | 2016年 / 307卷
关键词：
Sodium ion batteries; Mo3Sb7; Anode; Excellent cycling stability; ENERGY-STORAGE; HIGH-CAPACITY; THIN-FILMS; NEGATIVE ELECTRODES; LITHIUM-ION; NA-STORAGE; PERFORMANCE; MICROSPHERES; NANOCRYSTALS; NANOFIBERS;
D O I：
10.1016/j.jpowsour.2015.12.121
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Herein, carbon-coated Mo3Sb7 composite (Mo3Sb7@C) is successfully synthesized via a high temperature reaction accompanied by post-milling, and investigated as an anode material for sodium ion batteries. The as-prepared Mo3Sb7@C demonstrates a capacity of 400 mAh g(-1) at 0.2C (1C = 494 mA g(-1)), sustains 180 mAh g(-1) at 20C, as well as maintains 338 mAh g(-1) at 0.5C even after 800 cycles with a capacity retention of 91.8%, indicating an excellent cycling stability. The high performance of Mo3Sb7@C is expected to be ascribed to the buffer effect of Mo component for Sb associated with carbon coating and refined particle sizes of Mo3Sb7 during the cycling. In addition, a sodium ion full cell composing of Mo3Sb7@C anode and excessive Na3V2(PO4)(3)@C cathode is constructed to testify the performance and possibility of Mo3Sb7@C used as full cell anode. (C) 2015 Elsevier B.V. All rights reserved.
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收藏
页码：173 / 180
页数：8
相关论文
共 43 条
[1]   Mo3Sb7-C Composite Anodes for Lithium-Ion Batteries [J].
Applestone, Danielle ;
Yoon, Sukeun ;
Manthiram, Arumugam .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (38) :18909-18915
[2]   The reaction mechanism of FeSb2 as anode for sodium-ion batteries [J].
Baggetto, Loic ;
Hah, Hien-Yoong ;
Johnson, Charles E. ;
Bridges, Craig A. ;
Johnson, Jacqueline A. ;
Veith, Gabriel M. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (20) :9538-9545
[3]   Mo3Sb7 as a very fast anode material for lithium-ion and sodium-ion batteries [J].
Baggetto, Loic ;
Allcorn, Eric ;
Unocic, Raymond R. ;
Manthiram, Arumugam ;
Veith, Gabriel M. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (37) :11163-11169
[4]   AlSb thin films as negative electrodes for Li-ion and Na-ion batteries [J].
Baggetto, Loic ;
Marszewski, Michal ;
Gorka, Joanna ;
Jaroniec, Mietek ;
Veith, Gabriel M. .
JOURNAL OF POWER SOURCES, 2013, 243 :699-705
[5]   Predictions of particle size and lattice diffusion pathway requirements for sodium-ion anodes using η-Cu6Sn5 thin films as a model system [J].
Baggetto, Loic ;
Jumas, Jean-Claude ;
Gorka, Joanna ;
Bridges, Craig A. ;
Veith, Gabriel M. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (26) :10885-10894
[6]   Cu2Sb thin films as anode for Na-ion batteries [J].
Baggetto, Loic ;
Allcorn, Eric ;
Manthiram, Arumugam ;
Veith, Gabriel M. .
ELECTROCHEMISTRY COMMUNICATIONS, 2013, 27 :168-171
[7]   Facile synthesis and long cycle life of SnSb as negative electrode material for Na-ion batteries [J].
Darwiche, Ali ;
Sougrati, Moulay T. ;
Fraisse, Bernard ;
Stievano, Lorenzo ;
Monconduit, Laure .
ELECTROCHEMISTRY COMMUNICATIONS, 2013, 32 :18-21
[8]   Electrical Energy Storage for the Grid: A Battery of Choices [J].
Dunn, Bruce ;
Kamath, Haresh ;
Tarascon, Jean-Marie .
SCIENCE, 2011, 334 (6058) :928-935
[9]   Monodisperse Antimony Nanocrystals for High-Rate Li-ion and Na-ion Battery Anodes: Nano versus Bulk [J].
He, Meng ;
Kraychyk, Kostiantyn ;
Walter, Marc ;
Kovalenko, Maksym V. .
NANO LETTERS, 2014, 14 (03) :1255-1262
[10]   Antimony nanoparticles anchored on interconnected carbon nanofibers networks as advanced anode material for sodium-ion batteries [J].
Hou, Hongshuai ;
Jing, Mingjun ;
Yang, Yingchang ;
Zhang, Yan ;
Song, Weixin ;
Yang, Xuming ;
Chen, Jun ;
Chen, Qiyuan ;
Ji, Xiaobo .
JOURNAL OF POWER SOURCES, 2015, 284 :227-235
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