Stereoselective Cyclotrimerization of Enantiopure Iodonorbornenes Catalyzed by Pd Nanoclusters for C3 or C3v Symmetric syn-Tris(norborneno)benzenes

被引：30

作者：

Higashibayashi, Shuhei ^{[1
]}

Reza, A. F. G. Masud ^{[1
]}

Sakurai, Hidehiro ^{[1
,2
]}

机构：

[1] Inst Mol Sci, Res Ctr Mol Scale Nanosci, Okazaki, Aichi 4448787, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Tokyo 1020075, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 75卷 / 13期

关键词：

REGIOSELECTIVE CYCLOTRIMERIZATION; SYN; ENCAPSULATION; BROMOSTANNYLALKENES; BENZOCYCLOTRIMER; COORDINATION; GUESTS;

D O I：

10.1021/jo100710h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

C-3 or C-3v symmetric enantiopure syn-tris(norborneno)benzenes with various functional groups were synthesized through Pd-catalyzed cyclotrimerization of enantiopure iodonorbornenes. The generality of Pd-catalyzed cyclotrimerization for syn-tris(norborneno)benzenes were well-demonstrated.

引用

页码：4626 / 4628

页数：3

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