Manganese dioxide graphite composite electrodes formed via a low temperature method: Detection of hydrogen peroxide, ascorbic acid and nitrite

被引:50
作者
Sljukic, Biljana [1 ]
Compton, Richard G. [1 ]
机构
[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England
关键词
manganese dioxide; graphite powder; wet impregnation procedure; hydrogen peroxide; ascorbic acid; nitrite ions;
D O I
10.1002/elan.200703878
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Manganese dioxide modified carbon powder was prepared via a wet impregnation method from the solution of permanganate salt. After heating at 120 degrees C over night in air, the formation of manganese oxide was confirmed by cathodic stripping voltammetry. The synthesized material was used for fabrication of composite electrodes and their potential application in the field of electroanalysis investigated. The composite electrodes based on the manganese dioxide modified carbon powder proved to be useful as electrodes for detection of hydrogen peroxide, ascorbic acid and nitrite ions.
引用
收藏
页码:1275 / 1280
页数:6
相关论文
共 56 条
[1]   Electrocatalytic activity of Ce(III)-EDTA complex toward the oxidation of nitrite ion [J].
Abbaspour, A ;
Mehrgardi, MA .
TALANTA, 2005, 67 (03) :579-584
[2]   Configurations used in the design of screen-printed enzymatic biosensors.: A review [J].
Albareda-Sirvent, M ;
Merkoçi, A ;
Alegret, S .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 69 (1-2) :153-163
[3]  
[Anonymous], 1998, ELECTROANAL
[4]  
[Anonymous], 1994, ANAL ELECTROCHEMISTR
[5]   NO adsorption, desorption, and reduction by CH4 over Mn-ZSM-5 [J].
Aylor, AW ;
Lobree, LJ ;
Reimer, JA ;
Bell, AT .
JOURNAL OF CATALYSIS, 1997, 170 (02) :390-401
[6]   ELECTROCHEMICAL BEHAVIOR OF METALLIC OXIDES [J].
BRENET, JP .
JOURNAL OF POWER SOURCES, 1979, 4 (03) :183-190
[7]   A review of porous manganese oxide materials [J].
Brock, SL ;
Duan, NG ;
Tian, ZR ;
Giraldo, O ;
Zhou, H ;
Suib, SL .
CHEMISTRY OF MATERIALS, 1998, 10 (10) :2619-2628
[8]   Tetraalkylammonium manganese oxide gels: Preparation, structure, and ion-exchange properties [J].
Brock, SL ;
Sanabria, M ;
Nair, J ;
Suib, SL ;
Ressler, T .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (23) :5404-5410
[9]  
Campa MC, 1998, APPL CATAL B-ENVIRON, V18, P151
[10]   OXIDATIVE FLOW-INJECTION AMPEROMETRIC DETERMINATION OF NITRITE AT AN ELECTROCHEMICALLY PRE-TREATED GLASSY-CARBON ELECTRODE [J].
CHAMSI, AY ;
FOGG, AG .
ANALYST, 1988, 113 (11) :1723-1727