1-Benzyl-3-[(trimethylsilyl)methyl]benzimidazolium chloride monohydrate

被引:7
作者
Akkurt, Mehmet [1 ]
Celik, Ismail [2 ]
Kucukbay, Hasan [3 ]
Sireci, Nihat [4 ]
Buyukgungor, Orhan [5 ]
机构
[1] Erciyes Univ, Fac Arts & Sci, Dept Phys, TR-38039 Kayseri, Turkey
[2] Cumhuriyet Univ, Fac Arts & Sci, Dept Phys, TR-58140 Sivas, Turkey
[3] Inonu Univ, Fac Arts & Sci, Dept Chem, TR-44280 Malatya, Turkey
[4] Adiyaman Univ, Fac Arts & Sci, Dept Chem, TR-02040 Adiyaman, Turkey
[5] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Phys, TR-55139 Samsun, Turkey
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
ANTIMICROBIAL ACTIVITY; ANTIFUNGAL ACTIVITY; BIS-BENZIMIDAZOLES; ANTITUMOR-ACTIVITY; DERIVATIVES; BENZOTHIAZOLE; ANTIBACTERIAL; COMPLEXES;
D O I
10.1107/S1600536810024128
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C(18)H(23)N(2)Si(+)center dot Cl(-)center dot H(2)O, was synthesized from 1-[(trimethylsilyl)methyl]benzimidazole and benzyl chloride in dimethylformamide. The benzimidazole ring system is approximately planar, with a maximum deviation of 0.022 (2) angstrom, and makes an angle of 74.80 (12)degrees with the phenyl ring. The crystal packing is stabilized by O-H center dot center dot center dot Cl, C-H center dot center dot center dot Cl, C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions between symmetry-related molecules together with pi-pi stacking interactions between the imidazolium and benzene rings [centroid-centroid distance = 3.5690 (15) angstrom] and between the benzene rings [centroid-centroid distance = 3.7223 (14) angstrom].
引用
收藏
页码:O1770 / U302
页数:12
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