1-Benzyl-3-[(trimethylsilyl)methyl]benzimidazolium chloride monohydrate

被引：7

作者：

Akkurt, Mehmet ^{[1
]}

Celik, Ismail ^{[2
]}

Kucukbay, Hasan ^{[3
]}

Sireci, Nihat ^{[4
]}

Buyukgungor, Orhan ^{[5
]}

机构：

[1] Erciyes Univ, Fac Arts & Sci, Dept Phys, TR-38039 Kayseri, Turkey

[2] Cumhuriyet Univ, Fac Arts & Sci, Dept Phys, TR-58140 Sivas, Turkey

[3] Inonu Univ, Fac Arts & Sci, Dept Chem, TR-44280 Malatya, Turkey

[4] Adiyaman Univ, Fac Arts & Sci, Dept Chem, TR-02040 Adiyaman, Turkey

[5] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Phys, TR-55139 Samsun, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

ANTIMICROBIAL ACTIVITY; ANTIFUNGAL ACTIVITY; BIS-BENZIMIDAZOLES; ANTITUMOR-ACTIVITY; DERIVATIVES; BENZOTHIAZOLE; ANTIBACTERIAL; COMPLEXES;

D O I：

10.1107/S1600536810024128

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C(18)H(23)N(2)Si(+)center dot Cl(-)center dot H(2)O, was synthesized from 1-[(trimethylsilyl)methyl]benzimidazole and benzyl chloride in dimethylformamide. The benzimidazole ring system is approximately planar, with a maximum deviation of 0.022 (2) angstrom, and makes an angle of 74.80 (12)degrees with the phenyl ring. The crystal packing is stabilized by O-H center dot center dot center dot Cl, C-H center dot center dot center dot Cl, C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions between symmetry-related molecules together with pi-pi stacking interactions between the imidazolium and benzene rings [centroid-centroid distance = 3.5690 (15) angstrom] and between the benzene rings [centroid-centroid distance = 3.7223 (14) angstrom].

引用

页码：O1770 / U302

页数：12

共 50 条

[11] Bis{2-[(2-benzoylhydrazin-1-ylidene)-methyl]-6-methoxyphenolato}iron(III) chloride monohydrate [J].

Zou, Li-Fei ;

Ma, Yu-Qin ;

Yu, Gui-Miao ;

Gan, Feng-Jiao ;

Li, Yun-Hui .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 :M828-U1019

[12] 1,3-Disulfonic acid benzimidazolium chloride as an efficient and recyclable ionic liquid catalyst for the synthesis of 3,4-dihydropyrimidine-2-(1H)-ones/thiones [J].

Abbasi, Mohsen .

RESEARCH ON CHEMICAL INTERMEDIATES, 2016, 42 (04) :3303-3314

[13] SYNTHESIS OF 1-BENZYL-3-[4-(ARYL-1-PIPERAZINYL) CARBONYL]-1H-INDOLES. NOVEL LIGANDS WITH POTENTIAL D4 DOPAMINERGIC ACTIVITY [J].

Pessoa-Mahana, Hernan ;

Cuevas, Ignacio M. ;

Pessoa-Mahana, David ;

Araya-Maturana, Ramiro ;

Fajardo, Iriux Almodovar ;

Barria, Claudio Saitz .

JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2011, 56 (04) :866-869

[14] The Chloro(η2,η2-cycloocta-1,5-diene){1-benzyl-3-[(S)-2-hydroxy-1-methylethyl]benzimidazol-2-ylidene}rhodium(I) [J].

Sakaguchi, Satoshi ;

Matsuo, Shogo .

MOLBANK, 2024, 2024 (02)

[15] Crystal structure of 2-(ortho-hydroxyphenyl)-benzimidazolium chloride monohydrate, C13H13ClN2O2 [J].

Habarurema, Gratien ;

Gerber, Thomas I. A. ;

Hosten, Eric ;

Betz, Richard .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2014, 229 (04) :333-334

[16] Preparation and characterization of trimethylsilyl-substituted benzimidazole metal complexes and structural characterization of dichlorobis[1-(trimethylsilyl)methyl-1H-benzimidazole-N3]cobalt(II) [J].

Sireci, Nihat ;

Kucukbay, Hasan ;

Akkurt, Mehmet ;

Yalcin, Serife Pinar ;

Tahir, M. Nawaz ;

Ott, Holger .

JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (18) :3218-3228

[17] Synthesis, Characterization, and Structural Investigations of 1-(3-morpholinopropyl)-3-(4-chlorobenzoyl)thiourea monohydrate and 1-(3-morpholinopropyl)-3-(4-methylbenzoyl)thiourea monohydrate [J].

Razak, Ibrahim Abdul ;

Arshad, Suhana ;

Thanigaimani, Kaliyaperumal ;

Yusof, Mohd Sukeri Mohd ;

Abdullah, Sharifah Sakinah ;

Rahman, Azhar Abdul .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2015, 616 (01) :151-175

[18] Copper(I) bromide coordinated by the ionic liquid 1-[(diethyl amine)amine]ethyl-3-methyl imidazolium chloride to catalyze the atom transfer radical polymerization of methyl methacrylate in 1-allyl-3-methyl imidazolium chloride [J].

Xue, Teng ;

Tang, Erjun ;

Zhou, Jian ;

Han, Ruitao ;

Liu, Shaojie .

JOURNAL OF APPLIED POLYMER SCIENCE, 2017, 134 (46)

[19] The synthesis and characterization of 1-(Allyl)-3-(2-methylbenzyl) benzimidazolium chloride: FT-IR, NMR, and DFT computational investigation [J].

Serdaroglu, Goncagul ;

Sahin, Neslihan .

JOURNAL OF MOLECULAR STRUCTURE, 2019, 1178 :212-221

[20] 4-(5-Amino-1H-1,2,4-triazol-3-yl)pyridinium chloride monohydrate [J].

Chernyshev, Victor M. ;

Tarasova, Elena V. ;

Chernysheva, Anna V. ;

Rybakov, Victor B. .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 :O466-U1510

← 1 2 3 4 5 →