Photocatalytic metal-organic frameworks for organic transformations

被引：118
作者：
Yu, Xiao [1 ,2 ]
Wang, Le [2 ]
Cohen, Seth M. [2 ]
机构：
[1] Univ Calif San Diego, Dept Nanoengn, La Jolla, CA 92093 USA
[2] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA
来源：
CRYSTENGCOMM | 2017年 / 19卷 / 29期
基金：
美国国家科学基金会;
关键词：
VISIBLE-LIGHT PHOTOCATALYSIS; PHOTOREDOX CATALYSIS; AEROBIC OXIDATION; ARYL HALIDES; EFFICIENT; REDUCTION; ALKYLATION; NANOPARTICLES; AMINES; MOF;
D O I：
10.1039/c7ce00398f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-organic frameworks (MOFs) have attracted increasing attention for applications in heterogeneous photocatalysis. Modifications of metal nodes and organic linkers, as well as encapsulation of active species in the pores of MOFs enable the generation of photoactive materials for catalyzing organic transformations. MOF composites integrating noble metal nanoparticles or traditional photoactive semiconductors can combine the advantages of both materials, and also improve the photocatalytic performance via synergistic effects. In this Highlight, we discuss recent examples of photoactive MOFs and their use as photocatalysts for organic reactions.
引用
收藏
页码：4126 / 4136
页数：11
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