The Solubility Parameters of Ionic Liquids

被引:104
作者
Marciniak, Andrzej [1 ]
机构
[1] Warsaw Univ Technol, Dept Phys Chem, Fac Chem, PL-00664 Warsaw, Poland
关键词
ionic liquid; Hildebrand's solubility parameter; standard enthalpy of vaporization; INFINITE DILUTION MEASUREMENTS; INVERSE GAS-CHROMATOGRAPHY; ACTIVITY-COEFFICIENTS; ORGANIC SOLUTES; COMPOSITION DEPENDENCE; INTERNAL ENERGIES; BINARY-MIXTURES; TEMPERATURE; WATER; VAPORIZATION;
D O I
10.3390/ijms11051973
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The Hildebrand's solubility parameters have been calculated for 18 ionic liquids from the inverse gas chromatography measurements of the activity coefficients at infinite dilution. Retention data were used for the calculation. The solubility parameters are helpful for the prediction of the solubility in the binary solvent mixtures. From the solubility parameters, the standard enthalpies of vaporization of ionic liquids were estimated.
引用
收藏
页码:1973 / 1990
页数:18
相关论文
共 41 条
  • [1] Anthony JL, 2005, J PHYS CHEM B, V109, P6366, DOI 10.1021/jp0464041
  • [2] SOLUBILITY PARAMETERS
    BARTON, AFM
    [J]. CHEMICAL REVIEWS, 1975, 75 (06) : 731 - 753
  • [3] Dean J.A., 2001, Lange's Handbook of Chemistry, V15
  • [4] *DES I PHYS PROP D, 2009, DIPPR PROJ 801 FULL
  • [5] Measuring and predicting ΔvapH298 values of ionic liquids
    Deyko, Alexey
    Lovelock, Kevin R. J.
    Corfield, Jo-Anne
    Taylor, Alasdair W.
    Gooden, Peter N.
    Villar-Garcia, Ignacio J.
    Licence, Peter
    Jones, Robert G.
    Krasovskiy, Vladimir G.
    Chernikova, Elena A.
    Kustov, Leonid M.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (38) : 8544 - 8555
  • [6] Measurements of activity coefficients at infinite dilution of aromatic and aliphatic hydrocarbons, alcohols, and water in the new ionic liquid [EMIM][SCN] using GLC
    Domanska, Urszula
    Marciniak, Andrzej
    [J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2008, 40 (05) : 860 - 866
  • [7] Activity coefficients at infinite dilution measurements for organic solutes and water in the ionic liquid 1-butyl-3-methylimidazolium trifluoromethanesulfonate
    Domanska, Urszula
    Marciniak, Andrzej
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (35) : 11100 - 11105
  • [8] Activity coefficients at infinite dilution measurements for organic solutes and water in the ionic liquid 1-ethyl-3-methylimidazolium trifluoroacetate
    Domanska, Urszula
    Marciniak, Andrzej
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (41) : 11984 - 11988
  • [9] Activity Coefficients at Infinite Dilution Measurements for Organic Solutes and Water in the Ionic Liquid 1-Hexyl-3-methylimidazolium Thiocyanate
    Domanska, Urszula
    Marciniak, Andrzej
    Krolikowska, Marta
    Arasimowicz, Monika
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (07) : 2532 - 2536
  • [10] Phase behaviour and physico-chemical properties of the binary systems {1-ethyl-3-methylimidazolium thiocyanate, or 1-ethyl-3-methylimidazolium tosylate plus water, or plus an alcohol}
    Domanska, Urszula
    Krolikowska, Marta
    Krolikowski, Marek
    [J]. FLUID PHASE EQUILIBRIA, 2010, 294 (1-2) : 72 - 83