Growth and quantum confinement in AgI nanowires

被引:11
作者
Validzic, Ivana Lj. [1 ]
Jankovic, Ivana A. [1 ]
Mitric, Miodrag [1 ]
Bibic, Natasa [1 ]
Nedeljkovic, Jovan M. [1 ]
机构
[1] Vinca Inst Nucl Sci, Belgrade 11001, Serbia
关键词
AgI; nanowires; size quantization effect; nanomaterials; semiconductors; microemulsions;
D O I
10.1016/j.matlet.2006.11.114
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Silver iodide nanowires were synthesized in W/O microemulsions by using cyclohexane/Triton X-100/n-pentanol system. Most likely, surfactants form rod-like aggregates that can serve as template for growth of two dimensional nanomaterials. It was found that the length of the AgI nanowires increases as a function of aging time, while the diameter decreases. Final length of the AgI nanowires is several microns, while the diameter is smaller than 3 nm. Morphological changes are accompanied by optical and structural changes. Large blue shift of excitonic peak from bulk value at 420 to 326 nm was observed as a consequence of the size quantization effect. Decrease of diameter is followed by the amorphization of AgI nanowires. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:3522 / 3525
页数:4
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