Synthesis and X-ray diffraction data of 2-morpholino-2-(3,4,5-trimethoxyphenyl)acetonitrile, (C15H20N2O4)

被引：2

作者：

Quintana Mendoza, Jose H. ^{[1
]}

Henao, J. A. ^{[1
]}

Carreno Otero, Aurora L. ^{[2
]}

Kouznetsov, Vladimir V. ^{[2
]}

机构：

[1] Univ Ind Santander, Fac Ciencias, Escuela Quim, Grp Invest Quim Estruct GIQUE, Carrera 27,Calle 9 Ciudadela Univ, Bucaramanga 678, Colombia

[2] Univ Ind Santander, Lab Quim Organ & Biomol LQOBio, Parque Tecnol Guatiguara,Km 2 Via Refugio, Piedecuesta, Colombia

来源：

POWDER DIFFRACTION | 2016年 / 31卷 / 02期

关键词：

alpha-Aminonitriles; girgensohnine alkaloid; X-ray powder diffraction data; ALPHA-AMINONITRILES; STRECKER REACTION; POWDER; RELIABILITY; CRITERION; REAGENT;

D O I：

10.1017/S0885715616000075

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The alpha-aminonitrile, 2-morpholino-2-(3,4,5-trimethoxyphenyl)acetonitrile (C15H20N2O4), was prepared through a silica sulfuric acid-catalyzed Strecker reaction between 3,4,5-trimethoxybenzaldehyde, morpholine, and two different cyanide sources. Molecular characterization was performed by Fourier transform infrared spectroscopy, gas chromatography-mass spectrometry, (H-1, C-13 - mono and bidimensional) nuclear magnetic resonance; crystallographic characterization was completed by X-ray powder diffraction of polycrystalline samples. The title compounds crystallized in a monoclinic system and unit-cell parameters are reported [a = 13.904(2), b = 5.1696(6), c = 21.628(3) angstrom, beta = 104.31(1)degrees, unit-cell volume V = 1506.3(3) angstrom(3), Z = 4]. All measured lines were indexed with the P2(1)/a (No. 14) space group. (C) 2016 International Centre for Diffraction Data.

引用

页码：149 / 152

页数：4

共 47 条

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