Scanning electrochemical microscope characterization of thin film Pt-Ru alloys for fuel cell applications

被引:11
作者
Black, M
Cooper, J
McGinn, P [1 ]
机构
[1] Univ Notre Dame, Dept Chem & Biomol Engn, Notre Dame, IN 46556 USA
[2] Univ Notre Dame, Ctr Molecularly Engineered Mat, Notre Dame, IN 46556 USA
关键词
electrochemistry; catalysis; materials processing; films; fuel cell; combinatorial materials;
D O I
10.1016/j.ces.2004.08.047
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Thin film combinatorial libraries of potential fuel cell anode catalysts are formed by sputtering depositing through masks onto Si wafers. Libraries are examined for electrochemical activity with a scanning electrochemical microscope. Limitations in using scanning electrochemical microscopy for characterization of an array of fuel cell electrode materials are discussed. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4839 / 4845
页数:7
相关论文
共 26 条
[1]   Vegetarianism and vitamin B-12 (cobalamin) deficiency [J].
Antony, AC .
AMERICAN JOURNAL OF CLINICAL NUTRITION, 2003, 78 (01) :3-6
[2]  
Bard A.J., 2001, Scanning Electrochemical Microscopy
[3]   A multi-electrode probe for parallel imaging in scanning electrochemical microscopy [J].
Barker, AL ;
Unwin, PR ;
Gardner, JW ;
Rieley, H .
ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (01) :91-97
[4]   A low-loss composition region identified from a thin-film composition spread of (Ba1-x-ySrxCay) TiO3 [J].
Chang, H ;
Takeuchi, I ;
Xiang, XD .
APPLIED PHYSICS LETTERS, 1999, 74 (08) :1165-1167
[5]   Design and testing of a low-cost multichannel pseudopotentiostat for quantitative combinatorial electrochemical measurements on large electrode arrays [J].
Cumyn, VK ;
Fleischauer, MD ;
Hatchard, TD ;
Dahn, JR .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (06) :E15-E18
[6]   Economical sputtering system to produce large-size composition-spread libraries having linear and orthogonal stoichiometry variations [J].
Dahn, JR ;
Trussler, S ;
Hatchard, TD ;
Bonakdarpour, A ;
Mueller-Neuhaus, JR ;
Hewitt, KC ;
Fleischauer, M .
CHEMISTRY OF MATERIALS, 2002, 14 (08) :3519-3523
[8]   Construction and reactivity screening of a surface composition gradient for combinatorial discovery of electro-oxidation catalysts [J].
Jayaraman, S ;
Hillier, AC .
JOURNAL OF COMBINATORIAL CHEMISTRY, 2004, 6 (01) :27-31
[9]   Screening the reactivity of PtxRuy and PtxRuyMoz catalysts toward the hydrogen oxidation reaction with the scanning electrochemical microscope [J].
Jayaraman, S ;
Hillier, AC .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (22) :5221-5230
[10]   Construction and reactivity mapping of a platinum catalyst gradient using the scanning electrochemical microscope [J].
Jayaraman, S ;
Hillier, AC .
LANGMUIR, 2001, 17 (25) :7857-7864