Chemoselective noncatalytic addition of secondary phosphine chalcogenides to citral

被引：2

作者：

Gusarova, N. K. ^{[1
]}

Ivanova, N. I. ^{[1
]}

Konovalova, N. A. ^{[1
]}

Albanov, A. I. ^{[1
]}

Sinegovskaya, L. M. ^{[1
]}

Avseenko, N. D. ^{[1
]}

Sukhov, B. G. ^{[1
]}

Mikhaleva, A. I. ^{[1
]}

Gusarov, A. V. ^{[1
]}

Trofimov, B. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Favorsky Irkutsk Inst Chem, Irkutsk 664033, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2007年 / 77卷 / 03期

关键词：

D O I：

10.1134/S1070363207030139

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of secondary phosphine oxides, phosphine sulfides and phosphine selenides to 3,7-dimethyl-2,6-octadienal (citral) (48-50 degrees C, THF, argon) proceeds exclusively to the aldehyde group giving rise to new polyfunctional tertiary phosphine chalcogenides with diene and hydroxyl moieties in high preparative yield (up to 80%).

引用

页码：409 / 414

页数：6

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