Luminescence properties of Ba2NaNb5O15 crystals activated with Sm3+, Eu3+, Tb3+ or Dy3+ ions

被引:56
作者
Cavalli, Enrico [1 ]
Belletti, Alessandro [1 ]
Mahiou, Rachid [2 ,3 ]
Boutinaud, Philippe [3 ,4 ]
机构
[1] Univ Parma, Dipartimento Chim Gen Inorgan Chim Analit & Chim, I-43100 Parma, Italy
[2] Clermont Univ, UBP, Lab Mat Inorgan, F-63000 Clermont Ferrand, France
[3] Univ Clermont Ferrand 2, Photochim Mol & Macromol Lab, CNRS, UMR6002, F-63177 Clermont Ferrand, France
[4] Clermont Univ, ENSCCF, Lab Mat Inorgan, F-63000 Clermont Ferrand, France
关键词
Luminescence; Ba2NaNb5O15; Rare earths; Tungsten bronzes; Flux growth; Non-linear crystals; STRONTIUM BARIUM NIOBATE; OPTICAL-SPECTRA; INTENSITIES; GLASS;
D O I
10.1016/j.jlumin.2009.11.038
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Single Crystals of Ba2NaNb5O15 (BNN) singly doped with Sm3+, Eu3+, Tb3+ or Dy3+ have been grown by means of the flux growth method. Their visible emission and excitation spectra and the decay profiles of the luminescence have been measured at room temperature. All spectral features are significantly inhomogeneously broadened in consequence of the Structural disorder of the host and of the doping mechanisms. The analysis of the observed spectra allows formulating ail hypothesis about the site occupancy of the active ions in the BNN lattice. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:733 / 736
页数:4
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