Cobalt(II) single-molecule magnets

被引：533
|
作者：
Murrie, Mark [1 ]
机构：
[1] Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland
来源：
CHEMICAL SOCIETY REVIEWS | 2010年 / 39卷 / 06期
基金：
英国科学技术设施理事会; 英国工程与自然科学研究理事会;
关键词：
HIGH-SPIN MOLECULES; ANISOTROPY BARRIER; SMM BEHAVIOR; COMPLEXES; MAGNETIZATION; CLUSTERS; CAGE; CO; CHEMISTRY; SYMMETRY;
D O I：
10.1039/b913279c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This short tutorial review covers recent progress in the field of polynuclear cobalt(II)-based complexes, which display slow magnetic relaxation at low temperature. Cobalt(II) single-molecule magnets (SMMs) can display much larger magnetic anisotropies and hence, potentially higher blocking temperatures than SMMs based on ions where the zero-field splitting originates from a second order spin-orbit coupling, such as manganese(III).
引用
收藏
页码：1986 / 1995
页数：10
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