Rice Husk as the Source of Silicon/Carbon Anode Material and Stable Electrochemical Performance

被引:22
|
作者
Yu, Kaifeng [1 ]
Zhang, Hanxiang [1 ]
Qi, Hui [3 ]
Gao, Xuan [4 ]
Liang, Jicai [1 ,2 ]
Liang, Ce [1 ]
机构
[1] Jilin Univ, Coll Mat Sci & Engn, Minist Educ, Key Lab Automobile Mat, Changchun 130022, Jilin, Peoples R China
[2] Jilin Univ, Roll Forging Inst, Changchun 130022, Jilin, Peoples R China
[3] Jilin Univ, Hosp 2, Changchun 130041, Jilin, Peoples R China
[4] Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Jilin, Peoples R China
来源
CHEMISTRYSELECT | 2018年 / 3卷 / 19期
基金
中国博士后科学基金; 美国国家科学基金会;
关键词
lithium-ion batteries; anode material; Si/C composite; rice husk; LITHIUM-ION BATTERIES; HIGH-CAPACITY; COMPOSITE FILM; SI; LI; NANOPARTICLES; NANOWIRES; DESIGN; FIBERS;
D O I
10.1002/slct.201800650
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein, a magnesiothermic reduction strategy is employed to synthesize three-dimensional structured silicon/carbon (Si/C) material, using rice husk as raw materials. The composition and morphology of Si/C material are investigated by XRD, Raman, SEM and TEM. The unique structure benefits from the naturally conductive network of biomass carbon, and ensures the excellent electrochemistry performance. Utilizing for lithium-ion batteries (LIBs) anode material, this Si/C composite behaves good cycling stability (537 mA h g(-1) after 200 cycles at a current density of 0.1 A g(-1)), and enhanced rate capacity (640.31,521.6,415.88, and 331.71 mA h g(-1) at current densities of 0.1, 0.2,0.5 and 1 A g(-1), respectively). Our research exhibits a new strategy for preparing low-cost and environmental-friendly Si/C material and possesses enormous potential to be extended to other biomass anode materials.
引用
收藏
页码:5439 / 5444
页数:6
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