Doping of few-layered graphene and carbon nanotubes using ion implantation

被引:60
作者
Bangert, U. [1 ]
Bleloch, A. [2 ]
Gass, M. H. [2 ]
Seepujak, A. [1 ]
van den Berg, J. [3 ]
机构
[1] Univ Manchester, Sch Mat Sci, Manchester M1 7HS, Lancs, England
[2] Univ Liverpool, Sch Engn, Liverpool L69 3BX, Merseyside, England
[3] Univ Salford, Sch Comp Sci & Engn, Salford M5 4WT, Greater Manches, England
来源
PHYSICAL REVIEW B | 2010年 / 81卷 / 24期
关键词
ENERGY; ELECTRON; BUNDLES; SPECTROSCOPY; MOLECULES; EMISSION; PLASMONS; BEAMS; GAS;
D O I
10.1103/PhysRevB.81.245423
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Doping of nanostructured materials using a clean, efficient, and site-selective route such as ion implantation would be hugely desirable for realization of large-scale production methods. Here, ion implantation is used to create uniform impurity-atom densities which are both dose and spatially controlled within multiwalled carbon nanotubes and graphene. The technique is demonstrated for a range of dopants, including silver, representing a likely candidate for optical enhancement, and boron, which is predicted to introduce a plasmon within the visible-frequency regime. Electron energy-loss spectroscopy performed within an aberration-corrected scanning transmission electron microscope, in combination with high-angle-annular-dark-field imaging, is used to pinpoint and identify the bonding configuration of single foreign species within the matrix. © 2010 The American Physical Society.
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页数:11
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共 44 条
[1]   Macroscopic graphene membranes and their extraordinary stiffness [J].
Booth, Tim J. ;
Blake, Peter ;
Nair, Rahul R. ;
Jiang, Da ;
Hill, Ernie W. ;
Bangert, Ursel ;
Bleloch, Andrew ;
Gass, Mhairi ;
Novoselov, Kostya S. ;
Katsnelson, M. I. ;
Geim, A. K. .
NANO LETTERS, 2008, 8 (08) :2442-2446
[2]   Improved background removal method using principal components analysis for spatially resolved electron energy loss spectroscopy [J].
Borglund, N ;
Åstrand, PG ;
Csillag, S .
MICROSCOPY AND MICROANALYSIS, 2005, 11 (01) :88-96
[3]   π-plasmons in ion-irradiated multiwall carbon nanotubes [J].
Brzhezinskaya, MM ;
Baitinger, EM ;
Shnitov, VV .
PHYSICA B-CONDENSED MATTER, 2004, 348 (1-4) :95-100
[4]   Structure and electronic properties of potassium-doped single-wall carbon nanotubes [J].
Claye, AS ;
Nemes, NM ;
Jánossy, A ;
Fischer, JE .
PHYSICAL REVIEW B, 2000, 62 (08) :R4845-R4848
[5]   Solid-state electrochemistry of the Li single wall carbon nanotube system [J].
Claye, AS ;
Fischer, JE ;
Huffman, CB ;
Rinzler, AG ;
Smalley, RE .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (08) :2845-2852
[6]   Tunable nanoscale localization of energy on plasmon particle arrays [J].
de Waele, Rene ;
Koenderink, A. Femius ;
Polman, Albert .
NANO LETTERS, 2007, 7 (07) :2004-2008
[7]   Review of the doping of carbon nanotubes (multiwalled and single-walled) [J].
Duclaux, L .
CARBON, 2002, 40 (10) :1751-1764
[8]   Optical and field emission investigations for multiwalled carbon nanotubes with different functionalized groups [J].
Feng, W ;
Kamide, K ;
Zhou, F ;
Araki, H ;
Wang, XG ;
Yoshino, K .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2004, 43 (1A-B) :L36-L39
[9]   Chemical doping of single-wall carbon nanotubes [J].
Fischer, JE .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (12) :1079-1086
[10]   Electronic structure of multiwall boron nitride nanotubes [J].
Fuentes, GG ;
Borowiak-Palen, E ;
Pichler, T ;
Liu, X ;
Graff, A ;
Behr, G ;
Kalenczuk, RJ ;
Knupfer, M ;
Fink, J .
PHYSICAL REVIEW B, 2003, 67 (03)