Au/TiO2 catalyzed reductive amination of aldehydes and ketones using formic acid as reductant

被引：43

作者：

Liang, Shengzong ^{[1
]}

Monsen, Paige ^{[1
]}

Hammond, Gerald B. ^{[1
]}

Xu, Bo ^{[2
]}

机构：

[1] Univ Louisville, Dept Chem, Louisville, KY 40292 USA

[2] Donghua Univ, Coll Chem Chem Engn & Biotechnol, 2999 North Renmin Lu, Shanghai 201620, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2016年 / 3卷 / 04期

基金：

美国国家科学基金会;

关键词：

SUPPORTED GOLD NANOPARTICLES; TRANSFER HYDROGENATION; CARBONYL-COMPOUNDS; PRIMARY AMINES; SELECTIVE SYNTHESIS; ALIPHATIC-KETONES; SECONDARY AMINE; NITRO-COMPOUNDS; N-ALKYLATION; C-N;

D O I：

10.1039/c5qo00439j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The combination of commercial easily available Au/TiO2 as catalyst and cost-effective formic acid as reductant was able to render reductive amination of various carbonyl compounds. Aldehydes and ketones were converted into secondary and tertiary amines in good to excellent yields. The supported gold nanoparticles could be easily recycled by simple filtration.

引用

页码：505 / 509

页数：5

共 75 条

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