Synthesis and structure of a new molecular octahedral cluster complex Mo6Se8(Ph3P)6•2H2O

被引：5
作者：
Mironov, Yu. V. [1 ]
Kozhomuratova, Zh. S. [1 ]
Naumov, D. Yu. [1 ]
Fedorov, V. E. [1 ]
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2007年 / 48卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
molybdenum; octahedral cluster; triphenylphosphine; synthesis; crystal structure;
D O I：
10.1007/s10947-007-0058-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Mo6Se8(Ph3P)(6)center dot 2H(2)O cluster complex has been synthesized and its structure has been defined. The compound is triclinic, space group P (1) over bar, with unit cell parameters a = 14.3356(5) angstrom, b = 15.7882(4) angstrom, c = 25.3949(8) angstrom, alpha = 95.9750(10)degrees, beta = 91.1030(10)degrees, gamma = 112.2570(10)degrees, V = 5279.8(3) angstrom(3), Z = 2, rho(calc) = 1.772 g/cm(3). The complex has a molecular structure. The molybdenum atoms of the {Mo6Se8} cluster nucleus are coordinated by the phosphorus atoms of triphenylphosphine molecules.
引用
收藏
页码：383 / 387
页数：5
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