Non-metathetic behavior patterns of Grubbs' carbene

被引：172

作者：

Alcaide, B ^{[1
]}

Almendros, P

机构：

[1] Univ Complutense Madrid, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain

[2] CSIC, Inst Quim Organ Gen, Madrid 28006, Spain

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2003年 / 9卷 / 06期

关键词：

carbenes; heterogeneous catalysis; metathesis; ruthenium; synthetic methods;

D O I：

10.1002/chem.200390142

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Grubbs' carbene complex [Cl-2(Cy3P)(2)Ru=CHPh] and its second-generation counterpart [Cl-2(Im)(CY3P)Ru=CHPh] have demonstrated remarkable efficiency metathesizing olefins. Furthermore, a growing number of newly discovered catalytic processes mediated by this complex broaden its synthetic utility beyond olefin metathesis. In addition, the ready availability of these stable ruthenium-based catalysts coupled with their tolerance toward a wide variety of common functional groups make Grubbs' catalysts very convenient synthetic tools. This paper presents recent advances in the non-metathetic behavior patterns of Grubbs' carbene.

引用

页码：1259 / 1262

页数：4

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