Non-metathetic behavior patterns of Grubbs' carbene

被引：172
作者：
Alcaide, B [1 ]
Almendros, P
机构：
[1] Univ Complutense Madrid, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain
[2] CSIC, Inst Quim Organ Gen, Madrid 28006, Spain
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2003年 / 9卷 / 06期
关键词：
carbenes; heterogeneous catalysis; metathesis; ruthenium; synthetic methods;
D O I：
10.1002/chem.200390142
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Grubbs' carbene complex [Cl-2(Cy3P)(2)Ru=CHPh] and its second-generation counterpart [Cl-2(Im)(CY3P)Ru=CHPh] have demonstrated remarkable efficiency metathesizing olefins. Furthermore, a growing number of newly discovered catalytic processes mediated by this complex broaden its synthetic utility beyond olefin metathesis. In addition, the ready availability of these stable ruthenium-based catalysts coupled with their tolerance toward a wide variety of common functional groups make Grubbs' catalysts very convenient synthetic tools. This paper presents recent advances in the non-metathetic behavior patterns of Grubbs' carbene.
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收藏
页码：1259 / 1262
页数：4
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