Kinetic Features of the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition

被引：2

作者：

Zaremski, M. Yu. ^{[1
]}

Odintsova, V. V. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119991, Russia

来源：

POLYMER SCIENCE SERIES C | 2021年 / 63卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

MODEL ALKOXYAMINES; RATE ACCELERATION; HYDROGEN-TRANSFER; BLOCK-COPOLYMERS; BUTYL ACRYLATE; SIDE-REACTIONS; STYRENE; DECOMPOSITION; MECHANISM; IMIDAZOLINE;

D O I：

10.1134/S1811238221010069

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This review summarizes our and published data on the kinetics and mechanism of controlled radical polymerization of methacrylates mediated by nitroxide radicals. The reasons influencing the possibility or impossibility of the realization of radical polymerization of methyl methacrylate in the mode of reversible inhibition are analyzed. The main factors determining the specificity of the nitroxide-mediated polymerization of methacrylates are the interaction of nitroxides with growing radicals by the disproportionation mechanism, the Fischer hypereffect, a high rate of reinitiation, and an abnormally low rate of reversible termination.

引用

页码：11 / 28

页数：18

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