Self-assembly of an amphiphilic [2]rotaxane incorporating a tetrathiafulvalene unit

被引:56
作者
Jeppesen, JO
Perkins, J
Becher, J
Stoddart, JF
机构
[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
[2] Odense Univ, Univ So Denmark, Dept Chem, DK-5230 Odense M, Denmark
关键词
D O I
10.1021/ol006387s
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] The template-directed synthesis of a [2]rotaxane, in which a pi -electron deficient ring component-cyclobis(paraquat-p-phenylene)-is assembled around a pi -electron rich asymmetric monopyrrolotetrathiafulvalene unit on the rod section of an amphiphilic dumbbell component that is terminated by a hydrophilic dendritic stopper at one end and a hydrophobic tetraarylmethane stopper at the other end, is reported.
引用
收藏
页码:3547 / 3550
页数:4
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