Sparsely substituted chlorins as core constructs in chlorophyll analogue chemistry. Part 2: Derivatization

被引：49

作者：

Taniguchi, Masahiko ^{[1
]}

Ptaszek, Marcin ^{[1
]}

McDowell, Brian E. ^{[1
]}

Lindsey, Jonathan S. ^{[1
]}

机构：

[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

来源：

TETRAHEDRON | 2007年 / 63卷 / 18期

关键词：

chlorin; deuteration; bromination; metalation;

D O I：

10.1016/j.tet.2007.02.076

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stable chlorins bearing few or no substituents have been subjected to a variety of reactions including demetalation, magnesium insertion, oxochlorin formation, and bromination followed by Suzuki coupling. The kinetics of deuteration also have been determined for two oxochlorins and a series of chlorins bearing 0, 1, 2, or 3 meso-aryl substituents. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：3840 / 3849

页数：10

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