A Bridged Azobenzene Derivative as a Reversible, Light-Induced Chirality Switch

被引：89

作者：

Haberhauer, Gebhard ^{[1
]}

Kallweit, Christine ^{[1
]}

机构：

[1] Univ Duisburg Essen, Inst Organ Chem, Fac Chem, D-45117 Essen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 13期

关键词：

azo compounds; CD spectroscopy; isomerization; molecular switches; photochemistry; ELECTRONIC-PROPERTIES; MOLECULAR MOTORS; POLARIZED-LIGHT; LIQUID-CRYSTALS; ISOMERIZATION; BINAPHTHYLS; OLIGOMERS; MACHINES; ROTATION; POLYMER;

D O I：

10.1002/anie.200906731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A new trick for an old dog: The azoben-zene derivative 1 was used to demon-strate the light-induced spatially directed (unidirectional) tran cis isomerization for the first time. This important effect expands the range of applications for azobenzene derivatives. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2418 / 2421

页数：4

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