Antimony-doped tin dioxide nanometer powders prepared by the hydrothermal method

被引:37
作者
Miao, HY [1 ]
Ding, CS [1 ]
Luo, HJ [1 ]
机构
[1] Shaanxi Univ Sci & Technol, Mat Sci & Engn Coll, Xianyang 712081, Shaanxi, Peoples R China
关键词
tin dioxide; doped; nanometer powder; hydrothermal method;
D O I
10.1016/S0167-9317(03)00038-8
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Antimony doped tin dioxide nanometer powders have been prepared by the hydrothermal method using SbCl3 as the source of antimony. The doped powders are examined by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The crystal phase composition, particle size, crystal appearance characteristics and dispersity of the doped powders are investigated. The results show that doped powders are well crystallized and dispersed. The crystal phase composition of doped powders is SnO2 of tetragonal structure. The particle size of doped powders is similar to 3-12 nm. The crystal appearance characteristics of doped powders are mainly round. Antimony enters crystal lattice of tin dioxide via Sb3+. The doping effect of antimony is very good. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:142 / 146
页数:5
相关论文
共 10 条
[1]   Spectroelectrochemistry of highly doped nanostructured tin dioxide electrodes [J].
Boschloo, G ;
Fitzmaurice, D .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (16) :3093-3098
[2]   Ultrafiltration conducting membranes and coatings from redispersable, nanoscaled, crystalline SnO2:Sb particles [J].
Goebbert, C ;
Aegerter, MA ;
Burgard, D ;
Nass, R ;
Schmidt, H .
JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (01) :253-258
[3]   HYDROLYTIC CONDENSATION OF TIN(IV) ALKOXIDE COMPOUNDS TO FORM PARTICLES WITH WELL-DEFINED MORPHOLOGY [J].
GULLIVER, EA ;
GARVEY, JW ;
WARK, TA ;
HAMPDENSMITH, MJ ;
DATYE, A .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (05) :1091-1094
[4]   INFLUENCE OF ADDITIVES ON THE ELECTRICAL-PROPERTIES OF DENSE SNO2-BASED CERAMICS [J].
LAS, WC ;
DOLET, N ;
DORDOR, P ;
BONNET, JP .
JOURNAL OF APPLIED PHYSICS, 1993, 74 (10) :6191-6196
[5]   SEMICONDUCTOR GAS SENSORS [J].
MORRISON, SR .
SENSORS AND ACTUATORS, 1982, 2 (04) :329-341
[6]   STRUCTURAL AND FTIR SPECTROSCOPIC STUDIES OF GEL-XEROGEL-OXIDE TRANSITIONS OF SNO2 AND SNO2-SB POWDERS AND DIP-COATED FILMS PREPARED VIA INORGANIC SOL-GEL ROUTE [J].
OREL, B ;
LAVRENCICSTANGAR, U ;
CRNJAKOREL, Z ;
BUKOVEC, P ;
KOSEC, M .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1994, 167 (03) :272-288
[7]   Influence of the heating rate on the microstructure and on macroscopic properties of sol-gel SnO2:Sb coatings [J].
Pütz, J ;
Ganz, D ;
Gasparro, G ;
Aegerter, MA .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1998, 13 (1-3) :1005-1010
[8]   PRECIPITATION OF NANOMETER-SIZED UNIFORM CERAMIC PARTICLES IN EMULSIONS [J].
SAGER, W ;
EICKE, HF ;
SUN, WL .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1993, 79 (2-3) :199-216
[9]  
SHI E, 1996, INORG MATER, V11, P193
[10]   STUDY OF THE RAMAN-SPECTRUM OF NANOMETER SNO2 [J].
ZUO, J ;
XU, CY ;
LIU, XM ;
WANG, CS ;
WANG, CY ;
HU, Y ;
QIAN, YT .
JOURNAL OF APPLIED PHYSICS, 1994, 75 (03) :1835-1836