CAN-Catalyzed Rapid C-O Bond Formation towards α-Aminoxylation of Ketones

被引：25
作者：
Feng, Peng [1 ]
Song, Song [1 ]
Zhang, Li-He [1 ]
Jiao, Ning [1 ,2 ]
机构：
[1] Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China
[2] E China Normal Univ, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
来源：
SYNLETT | 2014年 / 25卷 / 19期
基金：
美国国家科学基金会;
关键词：
CAN; ketone; -aminoxylation; C-O bond formation; TEMPO; FREE-RADICAL POLYMERIZATIONS; PROCHIRAL RADICALS; NITROXYL RADICALS; CHEMISTRY; ALDEHYDES; TEMPO; ALKOXYAMINES;
D O I：
10.1055/s-0034-1379102
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple and efficient approach towards -oxyaminated ketones has been developed through CAN-catalyzed C-O bond formation with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO). The environmentally friendly transformation is practical due to the use of commercial available catalyst, easy operating procedures, the broad substrate scope, and short reaction time.
引用
收藏
页码：2717 / 2720
页数：4
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