The reduction process of phytic acid-silver ion system: A pulse radiolysis study

被引:6
作者
Joshi, Ravi [1 ]
Mukherjee, Tulsi [1 ]
机构
[1] Bhabha Atom Res Ctr, Radiat & Photochem Div, Chem Grp, Bombay 400085, Maharashtra, India
关键词
D O I
10.1016/j.radphyschem.2006.06.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Reduction of silver ion in a silver-phytic acid (1:1 ratio) system has been studied using pulse radiolysis technique. Time-resolved transformation of the intermediates, Ag+ -> Ag-0 -> Ag-2(+) -> Ag-3(2+), has been clearly observed in the reduction of silver-phytic acid (1: 1) system. The effect of phytic acid on the formation and decay of initial silver clusters has been also studied. The surface plasmon absorption band of stable silver nanoparticle (410 nm) and dynamic light scattering technique has been used to characterize the nanoparticles and measure the average size (R-av = 100 nm). (C) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:811 / 817
页数:7
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