Molecular iodine-mediated synthesis of thiocarbamates from thiols, isocyanides and water under metal-free conditions

被引：63

作者：

Bao, Wen-Hu ^{[1
]}

Wu, Chao ^{[1
]}

Wang, Jing-Ting ^{[1
]}

Xia, Wen ^{[2
]}

Chen, Ping ^{[2
]}

Tang, Zilong ^{[2
]}

Xu, Xinhua ^{[3
]}

He, Wei-Min ^{[1
,3
]}

机构：

[1] Hunan Univ Sci & Engn, Hunan Prov Engn Res Ctr Ginkgo Biloba, Yongzhou 425100, Peoples R China

[2] Hunan Univ Sci & Technol, Minist Educ, Key Lab Theoret Organ Chem & Funct Mol, Xiangtan 411201, Peoples R China

[3] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2018年 / 16卷 / 37期

基金：

中国国家自然科学基金;

关键词：

ONE-POT SYNTHESIS; QUINOLINE N-OXIDES; CARBON-MONOXIDE; BASE-FREE; AMINES; FACILE; SULFONYLATION; DERIVATIVES; ALCOHOLS; ALKYNES;

D O I：

10.1039/c8ob01820k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple and practical molecular iodine-mediated method for the efficient construction of thiocarbamates from isocyanides, thiols and water under metal-free and mild conditions has been developed. A variety of thiocarbamates were easily synthesized through this methodology, which has the advantages of simple operation, eco-friendly conditions, good functional group tolerance, and readily accessible raw materials.

引用

页码：8403 / 8407

页数：5

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