Partial dissociation of water leads to stable superstructures on the surface of zinc oxide

被引:249
作者
Meyer, B [1 ]
Marx, D
Dulub, O
Diebold, U
Kunat, M
Langenberg, D
Wöll, C
机构
[1] Ruhr Univ Bochum, Lehrstuhl Theoret Chem, D-44780 Bochum, Germany
[2] Ruhr Univ Bochum, Lehrstuhl Phys Chem 1, D-44780 Bochum, Germany
[3] Tulane Univ, Dept Phys, New Orleans, LA 70118 USA
关键词
D O I
10.1002/anie.200461696
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Half-dissociated: Experimental and computational findings conclude that water forms a highly ordered superstructure on defect-free surfaces of zinc oxide, in which every second water molecule is dissociated (see picture). The results are of general relevance for heterogeneous catalysis.
引用
收藏
页码:6642 / 6645
页数:4
相关论文
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