Novel molecularly hybridized polyethylene/silica composite materials: Polymerization of ethylene with supported titanocenes by mesoporous silicates

被引：0

作者：

Tajima, K ^{[1
]}

Ogawa, G ^{[1
]}

Aida, T ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2000年 / 38卷

关键词：

polyethylene; mesoporous silica; composite material; metallocene; template polymerization;

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel molecularly hybridized polyethylene/silica composite thin film was obtained by the gas-phase polymerization of ethylene with a titanocene-mounted mesoporous silica layer on a mica plate with mesoscopic pores arranged on the film surface. However, the use of titanocene-mounted hexagonal domains of mesoporous silica on a glass plate for the gas-phase polymerization of ethylene resulted in the formation of an islanded polyethylene/silica hybridized material. (C) 2000 John Wiley & Sons, Inc.

引用

页码：4821 / 4825

页数：5

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