Structure and magnetic properties of a decanuclear Mn2IIMn2IIIDy6 aggregate

被引：24
作者：
Majeed, Zeeshan [1 ]
Mondal, Kartik C. [1 ]
Kostakis, George E. [2 ]
Lan, Yanhua [1 ]
Anson, Christopher E. [1 ]
Powell, Annie K. [1 ,2 ]
机构：
[1] Karlsruhe Inst Technol, Inst Inorgan Chem, D-76131 Karlsruhe, Germany
[2] Karlsruhe Inst Technol, Inst Nanotechnol, D-76021 Karlsruhe, Germany
来源：
DALTON TRANSACTIONS | 2010年 / 39卷 / 20期
关键词：
SINGLE-MOLECULE MAGNETS; HIGH-SPIN MOLECULES; CRYSTAL-STRUCTURE; ANISOTROPY; COMPLEXES; LN; GLYCEROL; S=83/2; FAMILY; HYSTERESIS;
D O I：
10.1039/c000082e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Using glycerol (H(3)gly) as a primary ligand, the decanuclear aggregate [(Mn2Mn2Dy6III)-Mn-II-Dy-III(mu(3)-OH)(2)(Hgly)(4)(H(2)gly)(2)(PhCO2)(16)(H2O)(2)]center dot 10CH(3)CN (1) has been synthesised; it has a structure built up from two Mn2Dy2 heterocubane units linked through a central Dy-2(mu-benzoate)(4) paddle-wheel dimer and shows slow relaxation of its magnetisation.
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收藏
页码：4740 / 4743
页数：4
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