Trimerization of Ethylene to 1-Hexene with Titanium Complexes Bearing Phenoxy-Imine Ligands with Pendant Donors Combined with MAO

被引：80

作者：

Suzuki, Yasuhiko ^{[1
]}

Kinoshita, Shinsuke ^{[1
]}

Shibahara, Atsushi ^{[1
]}

Ishii, Seiichi ^{[1
]}

Kawamura, Kazumori ^{[1
]}

Inoue, Yoshihisa ^{[1
]}

Fujita, Terunori ^{[1
]}

机构：

[1] Mitsui Chem Inc, Res Ctr, Chiba 2990265, Japan

来源：

ORGANOMETALLICS | 2010年 / 29卷 / 11期

关键词：

OLEFIN POLYMERIZATION CATALYSTS; METAL OXIDATION-STATE; ETHENE TRIMERIZATION; ZIRCONIUM COMPLEXES; SELECTIVE TRIMERIZATION; CHROMIUM CATALYSTS; FI CATALYSTS; OLIGOMERIZATION; COPOLYMERIZATION; MECHANISM;

D O I：

10.1021/om1003368

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New Ti complexes bearing phenoxy-imine ligands with pendant aryl-OMe donors have been developed for ethylene trimerization to produce 1-hexene. These Ti complexes combined with methylaluminoxane selectively trimerize ethylene to form 1-hexene with exceptionally high activity (e.g., 6.59 tons of 1-hexenel((g of Ti) It))

引用

页码：2394 / 2396

页数：3

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