Trimerization of Ethylene to 1-Hexene with Titanium Complexes Bearing Phenoxy-Imine Ligands with Pendant Donors Combined with MAO

被引：80
|
作者：
Suzuki, Yasuhiko [1 ]
Kinoshita, Shinsuke [1 ]
Shibahara, Atsushi [1 ]
Ishii, Seiichi [1 ]
Kawamura, Kazumori [1 ]
Inoue, Yoshihisa [1 ]
Fujita, Terunori [1 ]
机构：
[1] Mitsui Chem Inc, Res Ctr, Chiba 2990265, Japan
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 11期
关键词：
OLEFIN POLYMERIZATION CATALYSTS; METAL OXIDATION-STATE; ETHENE TRIMERIZATION; ZIRCONIUM COMPLEXES; SELECTIVE TRIMERIZATION; CHROMIUM CATALYSTS; FI CATALYSTS; OLIGOMERIZATION; COPOLYMERIZATION; MECHANISM;
D O I：
10.1021/om1003368
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New Ti complexes bearing phenoxy-imine ligands with pendant aryl-OMe donors have been developed for ethylene trimerization to produce 1-hexene. These Ti complexes combined with methylaluminoxane selectively trimerize ethylene to form 1-hexene with exceptionally high activity (e.g., 6.59 tons of 1-hexenel((g of Ti) It))
引用
收藏
页码：2394 / 2396
页数：3
相关论文
共 50 条
  • [21] Homo- and Heteroligated Salicylaldiminato Titanium Complexes with Different Substituents Ortho to the Phenoxy Oxygens for Ethylene and Ethylene/1-Hexene (Co)polymerization
    Yao, Erdong
    Wang, Jianchun
    Chen, Zhongtao
    Ma, Yuguo
    MACROMOLECULES, 2014, 47 (23) : 8164 - 8170
  • [22] Pyridine bis(imine) cobalt or iron complexes for ethylene and 1-hexene (co)polymerisation
    Souane, R
    Isel, F
    Peruch, F
    Lutz, PJ
    COMPTES RENDUS CHIMIE, 2002, 5 (01) : 43 - 48
  • [23] Catalytic trimerization of ethylene by half-sandwich titanium complexes bearing a pendant ethereal group
    Wu, TZ
    Qian, YL
    Huang, JL
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 214 (02) : 227 - 229
  • [24] Synthesis of Ultrahigh-Molecular-Weight Ethylene-1-Hexene Copolymers with High Hexene Content via Living Polymerization with Fluorinated Bis(phenoxy-imine) Titanium(IV)
    Guo, Song
    Fan, Hong
    Bu, Zhiyang
    Li, Bo-Geng
    Zhu, Shiping
    MACROMOLECULAR RAPID COMMUNICATIONS, 2015, 36 (03) : 286 - 291
  • [25] Synthesis and evaluation of mono(phenoxy-imine) titanium complexes attached to a single polystyrene chain end for ethylene polymerization
    Dong, Zhen
    Yu, Feng
    Long, Chuanjiang
    Luo, Lang
    Feng, Sitong
    Cao, Kun
    Chen, Zhong-Ren
    POLYMER, 2024, 297
  • [26] Ethylene Polymerization with FI Complexes Having Novel Phenoxy-Imine Ligands: Effect of Metal Type and Complex Immobilization
    Krasuska, Agata
    Bialek, Marzena
    Czaja, Krystyna
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2011, 49 (07) : 1644 - 1654
  • [27] Monocyclopentadienyl phenoxy-imine and phenoxy-amine complexes of titanium and zirconium and their application as catalysts for 1-alkene polymerisation
    Bott, RKJ
    Hughes, DL
    Schormann, M
    Bochmann, M
    Lancaster, SJ
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 665 (1-2) : 135 - 149
  • [28] Titanium and Vanadium Complexes of Tridentate Phenoxy-Imine and Phenoxy-Amine Ligands and Their Application in the Ring-Opening Polymerization of Cyclic Esters
    Bialek, Marzena
    Klimasinska, Alicja
    Spaleniak, Grzegorz
    Dziuk, Blazej
    MOLECULES, 2024, 29 (01):
  • [29] First Cr(III)-SNS complexes and their use as highly efficient catalysts for the trimerization of ethylene to 1-hexene
    McGuinness, D.S. (wasserscheidp@itmc.rwth-aachen.de), 1600, American Chemical Society (125):
  • [30] First Cr(III)-SNS complexes and their use as highly efficient catalysts for the trimerization of ethylene to 1-hexene
    McGuinness, DS
    Wasserscheid, P
    Keim, W
    Morgan, D
    Dixon, JT
    Bollmann, A
    Maumela, H
    Hess, F
    Englert, U
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (18) : 5272 - 5273
12345