Trimerization of Ethylene to 1-Hexene with Titanium Complexes Bearing Phenoxy-Imine Ligands with Pendant Donors Combined with MAO

被引：80
|
作者：
Suzuki, Yasuhiko [1 ]
Kinoshita, Shinsuke [1 ]
Shibahara, Atsushi [1 ]
Ishii, Seiichi [1 ]
Kawamura, Kazumori [1 ]
Inoue, Yoshihisa [1 ]
Fujita, Terunori [1 ]
机构：
[1] Mitsui Chem Inc, Res Ctr, Chiba 2990265, Japan
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 11期
关键词：
OLEFIN POLYMERIZATION CATALYSTS; METAL OXIDATION-STATE; ETHENE TRIMERIZATION; ZIRCONIUM COMPLEXES; SELECTIVE TRIMERIZATION; CHROMIUM CATALYSTS; FI CATALYSTS; OLIGOMERIZATION; COPOLYMERIZATION; MECHANISM;
D O I：
10.1021/om1003368
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New Ti complexes bearing phenoxy-imine ligands with pendant aryl-OMe donors have been developed for ethylene trimerization to produce 1-hexene. These Ti complexes combined with methylaluminoxane selectively trimerize ethylene to form 1-hexene with exceptionally high activity (e.g., 6.59 tons of 1-hexenel((g of Ti) It))
引用
收藏
页码：2394 / 2396
页数：3
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