Na2CO3-promoted thioesterification via N-C bond cleavage of amides to construct thioester derivatives

被引：3
作者：
Tao, Jiasi [1 ,2 ,3 ]
Yu, Weijie [2 ,3 ]
Luo, Jin [4 ]
Wang, Tao [1 ,2 ,3 ]
Ge, Wanling [2 ,3 ]
Zhang, Ziwei [2 ,3 ]
Yang, Bingjie [2 ,3 ]
Xiong, Fei [1 ,2 ,3 ]
机构：
[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China
[2] Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang, Jiangxi, Peoples R China
[3] Jiangxi Normal Univ, Key Lab Chem Biol, Nanchang, Jiangxi, Peoples R China
[4] Jiangxi Normal Univ, Analyt & Testing Ctr, Nanchang 330022, Jiangxi, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2019年 / 43卷 / 11-12期
关键词：
selective N-C bond cleavage; stoichiometric Na2CO3; thioesters; transition-metal-free catalytic strategy; PALLADIUM-CATALYZED THIOCARBONYLATION; HIGHLY REGIOSELECTIVE THIOCARBONYLATION; PD-NHC PRECATALYST; SUZUKI-MIYAURA; EFFICIENT SYNTHESIS; CARBON-MONOXIDE; DECARBONYLATIVE CYANATION; COUPLING REACTION; KETONE SYNTHESIS; GENERAL-METHOD;
D O I：
10.1177/1747519819873514
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mild, efficient, and transition-metal-free catalytic strategy is developed to construct thioesters via selective N-C bond cleavage of Boc(2)-activated primary amides. This strategy is successfully carried out with stoichiometric Na2CO3 as the base and provides the corresponding products in moderate to excellent yields.
引用
收藏
页码：486 / 492
页数：7
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