New regioselective intercalation reactions

被引：0
作者：
O'Hare, D [1 ]
Fogg, A [1 ]
Green, VM [1 ]
Harvey, HG [1 ]
机构：
[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2000年 / 341卷
关键词：
intercalation; shape-selectivity; kinetics; X-ray diffraction;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ordered layered double hydroxide, [LiAl2(OH)(6)]Cl.2H(2)O exhibits shape-selective ion-exchange intercalation of dicarboxylate anions. Specific isomeric preferences can be controlled by varying the reaction temperatures. The intercalated guests can be quantitatively recovered from the host lattice with concomitant regeneration of the host offering a novel approach in separation science. To illustrate the potential of this new material in separation science, we describe the isolation of pure 1,4-benzenedicarboxylate and 2,6-naphthalenedicarboxylate from mixtures of their isomers. The neutral organic acids are both monomers in the synthesis or a range of important polyesters.
引用
收藏
页码：1099 / 1103
页数：5
相关论文
共 50 条
  • [41] Synthesis and characterization of new potential intercalation hosts -: barium arylphosphonates
    Svoboda, J.
    Zima, V.
    Benes, L.
    Melanova, K.
    Vlcek, M.
    Trchova, M.
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2008, 69 (5-6) : 1439 - 1443
  • [42] New application of intercalation on improving toughness of carbon/carbon composites
    Lu, JH
    Li, HJ
    Li, KZ
    Wang, LY
    Bai, RC
    Wang, C
    MATERIALS CHEMISTRY AND PHYSICS, 2006, 96 (2-3) : 376 - 380
  • [43] NEW POLYOXYETHYLENE INTERCALATION MATERIALS IN VANADIUM-OXIDE XEROGEL
    RUIZHITZKY, E
    ARANDA, P
    CASAL, B
    JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (05) : 581 - 582
  • [44] Synthesis, cytotoxicity, QSAR, and intercalation study of new diindenopyridine derivatives
    Miri, R
    Javidnia, K
    Hemmateenejad, B
    Azarpira, A
    Amirghofran, Z
    BIOORGANIC & MEDICINAL CHEMISTRY, 2004, 12 (10) : 2529 - 2536
  • [45] Graphite intercalation chemistry with large fluoroanions
    Yan, W
    Kabalnova, L
    Sukpirom, N
    Zhang, S
    Lerner, M
    JOURNAL OF FLUORINE CHEMISTRY, 2004, 125 (11) : 1703 - 1707
  • [46] Some Factors Influencing the Morphology of α-Zirconium Phosphate and its Intercalation Reactions with a Bifunctional Thioether Amine
    X. Duan
    F. Li
    J. He
    D.G. Evans
    Y.-B. Du
    Journal of Porous Materials, 2002, 9 : 5 - 16
  • [47] Effects of acetate and nitrate ions on radical and intercalation reactions initiated by CuZn hydroxy double salts
    Trakulmututa, Jirawat
    Uraisin, Kanchana
    Pornsuwan, Soraya
    Smith, Siwaporn Meejoo
    MATERIALS RESEARCH BULLETIN, 2023, 162
  • [48] INTERCALATION AND EXCHANGE-REACTIONS OF CLAY-MINERALS AND NON-CLAY LAYER COMPOUNDS
    LAGALY, G
    BENEKE, K
    COLLOID AND POLYMER SCIENCE, 1991, 269 (12) : 1198 - 1211
  • [49] Intercalation of halloysite: A Raman spectroscopic study
    Frost, RL
    Kristof, J
    CLAYS AND CLAY MINERALS, 1997, 45 (04) : 551 - 563
  • [50] Intercalation of wood charcoal with sulfuric acid
    Kodai Kuwata
    Yukie Saito
    Satoshi Shida
    Masamitsu Ohta
    Journal of Wood Science, 2009, 55 : 154 - 158
12345