Cube-shaped Porous Carbon Derived from MOF-5 as Advanced Material for Sodium-Ion Batteries

被引：126
作者：
Zou, Guoqiang [1 ]
Jia, Xinnan [1 ]
Huang, Zhaodong [1 ]
Li, Simin [1 ]
Liao, Hanxiao [1 ]
Hou, Hongshuai [1 ]
Huang, Lanping [2 ]
Ji, Xiaobo [1 ]
机构：
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
[2] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
来源：
ELECTROCHIMICA ACTA | 2016年 / 196卷
基金：
中国国家自然科学基金;
关键词：
cubic porous carbon; sodium-ion batteries; anode material; electrochemistry; METAL-ORGANIC FRAMEWORK; REDUCED GRAPHENE OXIDE; HIGH-SURFACE-AREA; ANODE MATERIALS; RATE CAPABILITY; LOW-COST; ENERGY-STORAGE; QUANTUM DOTS; NA; PERFORMANCE;
D O I：
10.1016/j.electacta.2016.03.016
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Cube-shaped porous carbon (CPC) was obtained from the carbonization of MOF-5 (Zn4O(OOCC6H4COO)(3)) crystals and shows abundant micro/mesopores, high mechanical strength, largest surface area (2316 m(2) g(-1), BET method) and good electrical conductivity (a high weight ratio 98.17/1.83 of C/O). When utilized as anode material for sodium-ion batteries, the CPC presents a high overall sodium storage capacity similar to 240 mAh g(-1) at a current density of 100 mA g(-1) after 100 cycles, and maintains a high specific capacity of 100 mAh g(-1) after 5000 cycles at a current density of 3200 mA g(-1). For the advantages of this unique carbon framework structure, the CPC might be a promising anode material for the application of SIBs. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：413 / 421
页数：9
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